Radiation induced chain addition of allylbenzene to 1,4-dioxane

1999-06-01
Nesterov, SV
Kucukyavuz, S
Önal, Ahmet Muhtar
Radiation induced chain addition of allylbenzene to 1,4-dioxane has been studied by IR-, UV-, mass-, NMR- and ESR-spectrometry. Efficiency of the addition depends on the concentration of monomer and it has an optimum at C-monom<0.125M. Apparently, upper concentration limit of the reaction is caused by absorbed energy transfer on the molecule of monomer followed by energy deactivation. Radiation-chemical yields of the product are 12 and 31 molec./100 eV for 0.125M and 0.07M solution, respectively. The value of G(prod) is an evidence of chain character of the process.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY

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Citation Formats
S. Nesterov, S. Kucukyavuz, and A. M. Önal, “Radiation induced chain addition of allylbenzene to 1,4-dioxane,” JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, pp. 953–957, 1999, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38033.