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Radiation induced chain addition of allylbenzene to 1,4-dioxane
Date
1999-06-01
Author
Nesterov, SV
Kucukyavuz, S
Önal, Ahmet Muhtar
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Radiation induced chain addition of allylbenzene to 1,4-dioxane has been studied by IR-, UV-, mass-, NMR- and ESR-spectrometry. Efficiency of the addition depends on the concentration of monomer and it has an optimum at C-monom<0.125M. Apparently, upper concentration limit of the reaction is caused by absorbed energy transfer on the molecule of monomer followed by energy deactivation. Radiation-chemical yields of the product are 12 and 31 molec./100 eV for 0.125M and 0.07M solution, respectively. The value of G(prod) is an evidence of chain character of the process.
Subject Keywords
Analytical chemistry
,
Spectroscopy
,
Public health, Environmental and Occupational Health
,
Nuclear Energy and Engineering
,
Pollution
,
Health, Toxicology and Mutagenesis
,
Radiology Nuclear Medicine and imaging
URI
https://hdl.handle.net/11511/38033
Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
DOI
https://doi.org/10.1007/bf02349881
Collections
Department of Chemistry, Article