Radiation induced chain addition of allylbenzene to 1,4-dioxane

Date

1999-06-01

Author

Nesterov, SV
Kucukyavuz, S
Önal, Ahmet Muhtar

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Radiation induced chain addition of allylbenzene to 1,4-dioxane has been studied by IR-, UV-, mass-, NMR- and ESR-spectrometry. Efficiency of the addition depends on the concentration of monomer and it has an optimum at C-monom<0.125M. Apparently, upper concentration limit of the reaction is caused by absorbed energy transfer on the molecule of monomer followed by energy deactivation. Radiation-chemical yields of the product are 12 and 31 molec./100 eV for 0.125M and 0.07M solution, respectively. The value of G(prod) is an evidence of chain character of the process.

Subject Keywords

Analytical chemistry, Spectroscopy, Public health, Environmental and Occupational Health, Nuclear Energy and Engineering, Pollution, Health, Toxicology and Mutagenesis, Radiology Nuclear Medicine and imaging

URI

https://hdl.handle.net/11511/38033

Collections

Department of Chemistry, Article