Gamma-radiation initiated addition of allylbenzene to the morpholine

Date

1999-10-01

Author

Nesterov, SV
Kucukyavuz, S
Önal, Ahmet Muhtar

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Radiation induced addition of allylbenzene to morpholine in liquid state was investigated by UV-, IR-spectroscopy and GS/mass spectrometry. Conversion of monomer depends on its initial concentration in the solution and this value is maximum for 0.05M solution. Radiation chemical yield of the product, G(prod), increases with concentration of allylbenzene and for 0.15M solution it is equal approximately 9.7 molec/100 eV. This value points on chain character of the process. Final product was identified by electron impact mass-spectrometry. The scheme of the EI induced fragmentation of product is proposed.

Subject Keywords

Analytical Chemistry, Spectroscopy, Public Health, Environmental and Occupational Health, Nuclear Energy and Engineering, Pollution, Health, Toxicology and Mutagenesis, Radiology Nuclear Medicine and imaging

URI

https://hdl.handle.net/11511/44418

Collections

Department of Chemistry, Article