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Gamma-radiation initiated addition of allylbenzene to the morpholine

1999-10-01
Nesterov, SV
Kucukyavuz, S
Önal, Ahmet Muhtar
Radiation induced addition of allylbenzene to morpholine in liquid state was investigated by UV-, IR-spectroscopy and GS/mass spectrometry. Conversion of monomer depends on its initial concentration in the solution and this value is maximum for 0.05M solution. Radiation chemical yield of the product, G(prod), increases with concentration of allylbenzene and for 0.15M solution it is equal approximately 9.7 molec/100 eV. This value points on chain character of the process. Final product was identified by electron impact mass-spectrometry. The scheme of the EI induced fragmentation of product is proposed.