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Gamma-radiation initiated addition of allylbenzene to the morpholine
Date
1999-10-01
Author
Nesterov, SV
Kucukyavuz, S
Önal, Ahmet Muhtar
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Radiation induced addition of allylbenzene to morpholine in liquid state was investigated by UV-, IR-spectroscopy and GS/mass spectrometry. Conversion of monomer depends on its initial concentration in the solution and this value is maximum for 0.05M solution. Radiation chemical yield of the product, G(prod), increases with concentration of allylbenzene and for 0.15M solution it is equal approximately 9.7 molec/100 eV. This value points on chain character of the process. Final product was identified by electron impact mass-spectrometry. The scheme of the EI induced fragmentation of product is proposed.
Subject Keywords
Analytical Chemistry
,
Spectroscopy
,
Public Health, Environmental and Occupational Health
,
Nuclear Energy and Engineering
,
Pollution
,
Health, Toxicology and Mutagenesis
,
Radiology Nuclear Medicine and imaging
URI
https://hdl.handle.net/11511/44418
Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
DOI
https://doi.org/10.1007/bf02345898
Collections
Department of Chemistry, Article