Karakaya, İshak
To further the understanding of electrolytes of value in industrial magnesium electrolysis, the reversible emf for the formation of in fused salts containing and was studied. The data made possible the calculation of thermodynamic solution properties which were used with other data to construct features of the ternary phase diagram. The multiple discrete complex anion (MDCA) model was tested against the thermodynamic findings from the present study. Reasonable agreement was obtained between the experimental properties and the values calculated from the model.


Electrochemical Behavior of Hydrazine Borane in Methanol Solution
Ozhava, Derya; Önal, Ahmet Muhtar; Özkar, Saim (The Electrochemical Society, 2014-01-01)
Electrochemical behavior of hydrazine borane (HB) was investigated on gold electrode in 0.5 M LiClO4 solution in methanol using cyclic voltammetry, electrochemical impedance spectroscopy (EIS) and chronoamperometry. Two irreversible peaks at 164 and 530 mV are attributed to direct electro-oxidation of HB on gold electrode in methanol. Both EIS results and CV data at different scan rates indicate a diffusion controlled electron transfer reaction. Furthermore, the Tafel slope (b = 0.191 V) and charge transfer...
Syntheses and Electrochemical Characterization of Low Oxidation Potential Nitrogen Analogs of Pedot as Electrochromic Materials
Hacioglu, Serife O.; Yigit, Deniz; Ermis, Emel; Soylemez, Saniye; GÜLLÜ, Mustafa; Toppare, Levent Kamil (The Electrochemical Society, 2016-01-01)
In this study, the electropolymerization of ethyl andmethyl substituted asymmetrical nitrogen analogs of 3,4-ethylenedioxythiophene (OEt and OMe) were synthesized, characterized and their electrochemical properties were investigated. Both polymers (POEt and POMe) were synthesized electrochemically and characterized using spectroelectrochemical technique to determine optical changes of the resulting polymer films. Electrochemical studies demonstrated that these polymers exhibited a significantly low oxidatio...
Efficient Ceria-Supported Rhodium Nanoparticles as an Electrocatalyst for Hydrogen Evolution
Akbayrak, Merve; Önal, Ahmet Muhtar (The Electrochemical Society, 2019-12-13)
Rh-0/CeO2 catalystwas prepared by the reduction of Rh+3 ions on CeO2 surface and characterized by transmission electron microscopy, inductively coupled plasma optical emission spectrometry, X-ray photoelectron spectroscopy and powder X-ray diffractometry techniques. To investigate its electrocatalytic activity for H-2 evolution reaction, a glassy carbon electrode (GCE) was modified with Rh-0/CeO2. The modified electrode was found to exhibit a high electrocatalytic activity (turnover frequency (TOF): 1.56 s(...
Karakaya, İshak (The Electrochemical Society, 1986-04-01)
A formation cell was used to study the thermodynamic properties associated with the formation of pure liquid and dissolved in binary melts. The data were used to infer the enthalpy and entropy of mixing. These measurements are shown to be consistent with the known phase diagram.
Sequential Deposition of Electrochromic MoO3 Thin Films with High Coloration Efficiency and Stability
Turel, Onur; Hacioglu, Serife O.; Coskun, Sahin; Toppare, Levent Kamil; Ünalan, Hüsnü Emrah (The Electrochemical Society, 2017-01-01)
Effect of thin film deposition route on the morphology and performance of molybdenum oxide (MoO3) based electrochromic devices was investigated. For the deposition of thin films, a sequential deposition method, which includes ultrasonic spray pyrolysis (USP) and thermal evaporation methods was used. Films deposited solely using either USP or thermal evaporation method were used as control samples. Following deposition, MoO3 thin films were then characterized using X-ray diffraction, X-ray photoelectron spec...
Citation Formats
J. ZHU, İ. Karakaya, and W. THOMPSON, “PARTIAL MOLAR PROPERTIES OF MGCL2 IN MGCL2-KCL-CACL2 MELTS,” JOURNAL OF THE ELECTROCHEMICAL SOCIETY, pp. 122–126, 1988, Accessed: 00, 2020. [Online]. Available: