Sequential Deposition of Electrochromic MoO3 Thin Films with High Coloration Efficiency and Stability

Date

2017-01-01

Author

Turel, Onur
Hacioglu, Serife O.
Coskun, Sahin
Toppare, Levent Kamil
Ünalan, Hüsnü Emrah

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

38
views

0
downloads

Effect of thin film deposition route on the morphology and performance of molybdenum oxide (MoO3) based electrochromic devices was investigated. For the deposition of thin films, a sequential deposition method, which includes ultrasonic spray pyrolysis (USP) and thermal evaporation methods was used. Films deposited solely using either USP or thermal evaporation method were used as control samples. Following deposition, MoO3 thin films were then characterized using X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and atomic force microscopy. Surface characteristics and chemical structure of the deposited thin films were found to depend extensively on the deposition route. Electrochromic performance and reversibility of the samples were evaluated using ultraviolet-visible spectrophotometer and cyclic voltammetry. Sample prepared by USP method showed low coloration efficiency (16 cm(2) C-1), but high stability. In contrast, sample prepared by thermal evaporation had high coloration efficiency (30 cm(2) C-1), but low stability. Sample prepared by sequential deposition method showed the highest coloration efficiency (33 cm(2) C-1) among other samples and maintained its stability with cycling. The sequential deposition route investigated in this work is highly promising and might be extended to other metal oxide systems. (c) 2017 The Electrochemical Society.

Subject Keywords

Renewable Energy, Sustainability and the Environment, Electrochemistry, Materials Chemistry, Electronic, Optical and Magnetic Materials, Surfaces, Coatings and Films, Condensed Matter Physics

URI

https://hdl.handle.net/11511/48039

Journal

JOURNAL OF THE ELECTROCHEMICAL SOCIETY

DOI

https://doi.org/10.1149/2.1201714jes

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Efficient Ceria-Supported Rhodium Nanoparticles as an Electrocatalyst for Hydrogen Evolution Akbayrak, Merve; Önal, Ahmet Muhtar (The Electrochemical Society, 2019-12-13) Rh-0/CeO2 catalystwas prepared by the reduction of Rh+3 ions on CeO2 surface and characterized by transmission electron microscopy, inductively coupled plasma optical emission spectrometry, X-ray photoelectron spectroscopy and powder X-ray diffractometry techniques. To investigate its electrocatalytic activity for H-2 evolution reaction, a glassy carbon electrode (GCE) was modified with Rh-0/CeO2. The modified electrode was found to exhibit a high electrocatalytic activity (turnover frequency (TOF): 1.56 s(...
Syntheses and Electrochemical Characterization of Low Oxidation Potential Nitrogen Analogs of Pedot as Electrochromic Materials Hacioglu, Serife O.; Yigit, Deniz; Ermis, Emel; Soylemez, Saniye; GÜLLÜ, Mustafa; Toppare, Levent Kamil (The Electrochemical Society, 2016-01-01) In this study, the electropolymerization of ethyl andmethyl substituted asymmetrical nitrogen analogs of 3,4-ethylenedioxythiophene (OEt and OMe) were synthesized, characterized and their electrochemical properties were investigated. Both polymers (POEt and POMe) were synthesized electrochemically and characterized using spectroelectrochemical technique to determine optical changes of the resulting polymer films. Electrochemical studies demonstrated that these polymers exhibited a significantly low oxidatio...
PARTIAL MOLAR PROPERTIES OF MGCL2 IN MGCL2-KCL-CACL2 MELTS ZHU, J; Karakaya, İshak; THOMPSON, WT (The Electrochemical Society, 1988-01-01) To further the understanding of electrolytes of value in industrial magnesium electrolysis, the reversible emf for the formation of in fused salts containing and was studied. The data made possible the calculation of thermodynamic solution properties which were used with other data to construct features of the ternary phase diagram. The multiple discrete complex anion (MDCA) model was tested against the thermodynamic findings from the present study. Reasonable agreement was obtained between the experimen...
Electrochemical Behavior of Hydrazine Borane in Methanol Solution Ozhava, Derya; Önal, Ahmet Muhtar; Özkar, Saim (The Electrochemical Society, 2014-01-01) Electrochemical behavior of hydrazine borane (HB) was investigated on gold electrode in 0.5 M LiClO4 solution in methanol using cyclic voltammetry, electrochemical impedance spectroscopy (EIS) and chronoamperometry. Two irreversible peaks at 164 and 530 mV are attributed to direct electro-oxidation of HB on gold electrode in methanol. Both EIS results and CV data at different scan rates indicate a diffusion controlled electron transfer reaction. Furthermore, the Tafel slope (b = 0.191 V) and charge transfer...
Investigation of photovoltaic properties of amorphous InSe thin film based Schottky devices Yilmaz, K.; Parlak, Mehmet; Ercelebi, C. (IOP Publishing, 2007-12-01) In this study, device behavior of amorphous InSe thin films was investigated through I-V, C-V and spectral response measurements onto SnO2/p-InSe/metal Schottky diode structures. Various metal contacts such as Ag, Au, Al, In and C were deposited onto amorphous p-InSe films by the thermal evaporation technique. The best rectifying contact was obtained in a SnO2/p-InSe/Ag Schottky structure from I-V measurements, while the Au contact had poor rectification. Other metal contacts (Al, In and C) showed almost oh...

Citation Formats

O. Turel, S. O. Hacioglu, S. Coskun, L. K. Toppare, and H. E. Ünalan, “Sequential Deposition of Electrochromic MoO3 Thin Films with High Coloration Efficiency and Stability,” JOURNAL OF THE ELECTROCHEMICAL SOCIETY, pp. 0–0, 2017, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48039.