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Resolution of (±)-2-substituted norbornadiene and hexachloronorbornadiene derivatives using CCL and PLE
Date
2001-09-13
Author
Tanyeli, Cihangir
ÇELİKEL, Gamze
Akhmedov, Idris Mecidolu
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(+/-)-2-Hydroxymethylbicyclo[2.2.1]hepta-2,5-diene. (+/-)-2-acetoxymethylbicyclo[2.2.1]hepta-2,5-diene and their hexachlorinated derivatives were resolved via CCL- and PLE-catalysed hydrolysis to afford enantiomerically enriched products with e.e.s of 61-93%. The absolute configurations were determined by transforming 2-hydroxymethylbicyclo[2.2.1]hepta-2,5-diene into the 2-formylbicyclo[2.2.1]hepta-2,5-diene with known absolute configuration.
Subject Keywords
Ketones
URI
https://hdl.handle.net/11511/40101
Journal
Tetrahedron Asymmetry
DOI
https://doi.org/10.1016/s0957-4166(01)00413-x
Collections
Department of Chemistry, Article