Nanoalumina supported palladium(0) nanoparticle catalyst for releasing H-2 from dimethylamine borane

Date

2019-09-01

Author

KARABOĞA, SEDA
Özkar, Saim

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Palladium(II) 2,4-pentanedionate, impregnated on alumina nanopowder, was reduced by dimethylamine borane (DMAB) forming Pd(0) nanoparticles (NPs) at room temperature. Pd(0) NPs could be isolated from solution and characterized by ATR-IR, UV-vis, XRD, SEM, TEM, XPS and BET. The results obtained from TEM images reveal the formation of palladium(0) nanoparticles on gamma-alumina, having a mean particle size of 7.1 +/- 2.6 nm. Alumina supported Pd(0) NPs with various metal loadings were employed as catalyst in dehydrogenation of DMAB at room temperature and the sample with 5.0% wt. Pd provides the highest turnover frequency (TOF = 73 h(-1)) at 25.0 +/- 0.5 degrees C. Kinetics of the catalytic dehydrogenation was also investigated depending on Pd concentration and temperature to determine the kinetic parameters of the H-2 release reaction.

Subject Keywords

Hydrogen generation, Palladium(0) nanoparticles, Heterogeneous catalyst, Dimethylamine borane, Dehydrogenation

URI

https://hdl.handle.net/11511/41006

Journal

APPLIED SURFACE SCIENCE

DOI

https://doi.org/10.1016/j.apsusc.2019.05.087

Collections

Department of Chemistry, Article

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Citation Formats

S. KARABOĞA and S. Özkar, “Nanoalumina supported palladium(0) nanoparticle catalyst for releasing H-2 from dimethylamine borane,” APPLIED SURFACE SCIENCE, pp. 433–441, 2019, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/41006.