Ruthenium(0) nanoparticles supported on silica coated Fe3O4 as magnetically separable catalysts for hydrolytic dehydrogenation of ammonia borane

Date

2018-08-09

Author

Sarica, Esra
AKBAYRAK, SERDAR
Özkar, Saim

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Ruthenium(0) nanoparticles supported on bare or silica-coated magnetite are prepared by impregnation of ruthenium(III) ions followed by their reduction with aqueous solution of sodium borohydride on the surface of support. These magnetically isolable catalysts are used in hydrogen generation from the hydrolysis of ammonia borane at room temperature. They conserve their initial catalytic activity even after the fifth reuse in the hydrolysis reaction, Ruthenium(0) nanoparticles supported on bare magnetite and silica-coated magnetite provide turnover frequency values of 29 min(-1) and 127 min(-1) and in hydrolytic dehydrogenation of ammonia borane at 25.0 +/- 0.1 degrees C. Thus, coating of the surface of magnetite with silica results in a significant enhancement in catalytic activity of ruthenium(0) nanoparticles in hydrogen generation from the hydrolysis of ammonia borane. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Subject Keywords

Fuel Technology, Renewable Energy, Sustainability and the Environment, Energy Engineering and Power Technology, Condensed Matter Physics

URI

https://hdl.handle.net/11511/41688

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

DOI

https://doi.org/10.1016/j.ijhydene.2018.06.058

Collections

Department of Chemistry, Article

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Citation Formats

E. Sarica, S. AKBAYRAK, and S. Özkar, “Ruthenium(0) nanoparticles supported on silica coated Fe3O4 as magnetically separable catalysts for hydrolytic dehydrogenation of ammonia borane,” INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, pp. 15124–15134, 2018, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/41688.