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Copper-catalyzed asymmetric conjugate addition of diethylzinc to substituted chalcones using a chiral phosphine ligand

2011-09-15
Doğan, Özdemir
Bulut, Adnan
Polat, Savas
Tecimer, M. Ali
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Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
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A series of chiral phosphine PFAM and phosphine oxide POFAM ligands were studied for the copper-catalyzed asymmetric diethylzinc addition to enones. One of these ligands, PFAM2, was an efficient catalyst with a variety of enones to give conjugate addition products in up to 96% yield and 92% ee.
Zinc, Reagents, Fam, Acyclic enones, Enantioselective addition
https://hdl.handle.net/11511/41784

Department of Chemistry, Article
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