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Efficient synthesis of ferrocenylenones by Friedel-Crafts acylation with EtAlCl2-Me3Al
Date
2005-01-17
Author
Doğan, Özdemir
SENOL, VOLKAN
ZEYTİNCİ, SERHAT
KOYUNCU, HASAN
BULUT, ADNAN
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Efficient synthesis of ferrocenyl en ones using a Friedel-Crafts acylation reaction is described. Acryloyl, methacryloyl, crotonoyl, cinnamoyl, and beta-methylcrotonoyl chlorides react with ferrocene in the presence of a Lewis acid (EtAlC2 or EtAlCl2-Me3Al) to give the corresponding ferrocenyl en ones (acryloyl, methacryloyl, crotonoyl, cinnamoyl, and methylcrotonoylferrocenes) in good isolated yields. Besides ferrocenylenones, chloroactylferrocene is also synthesised by this method.
Subject Keywords
Ferrocenylenones
,
Friedel-Crafts acylation
,
Ethylaluminum dichloride
,
Lewis acid
URI
https://hdl.handle.net/11511/41976
Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
DOI
https://doi.org/10.1016/j.jorganchem.2004.09.055
Collections
Department of Chemistry, Article