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Novel conversion of thiols into disulfides, via S-nitrosothiol intermediates using trichloronitromethane
Date
1999-10-15
Author
Demir, Ayhan Sıtkı
Igdir, AC
Mahasneh, AS
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
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An efficient oxidative coupling of thiols to give disulfides via thionitrite (S-nitrosothiol) intermediate is described using trichloronitromethane as an efficient reagent in organic solvents and water. Cysteine and glutathione are converted into the corresponding disulfides in water in high yields.
Subject Keywords
Disulfides
,
Thionitroso compounds
,
Thiols
,
Nitroso compounds
URI
https://hdl.handle.net/11511/56550
Journal
TETRAHEDRON
DOI
https://doi.org/10.1016/s0040-4020(99)00722-x
Collections
Department of Chemistry, Article