Silafluorene-based polymers for electrochromic and polymer solar cell applications

Date

2015-07-01

Author

ERLIK, Ozan
UNLU, Naime A.
HIZALAN, Gonul
HACIOGLU, Serife O.
COMEZ, Seda
Yildiz, Esra D.
Toppare, Levent Kamil
Çırpan, Ali

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In this study, four novel silafluorene (SiF) and benzotriazole (Btz) bearing conjugated polymers are synthesized. In the context of electrochemical and optical studies, these polymers are promising materials both for electrochromic device (ECD) and polymer solar cell (PSC) applications. All of the polymers are ambipolar (both p- and n-dopable) and multichromic. Electrochemistry experiments indicate that incorporation of selenophene instead of thiophene unit increases the HOMO energy level of the polymers. Power conversion efficiency of the PSCs reached 1.75% for PTBTSiF, 1.55% for PSBSSiF, 2.57% for PBTBTSiF, and 1.82% for PBSBSSiF. The hole mobilities of the polymers are estimated through space charge limited current (SCLC) model. PBTBTSiF has the highest hole mobility as 2.44 x 10(-3) cm(2) V s(-1). (c) 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 1541-1547

Subject Keywords

Organic Chemistry, Materials Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/44635

Collections

Department of Chemistry, Article