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ANODIC POTENTIAL HOMO ENERGY RELATIONS OF FLUORENE DERIVATIVES

1993-09-01
SEN, S
CELEBI, N
TURKER, L
Önal, Ahmet Muhtar
Anodic oxidation peak potentials (E(p,a)) of some fluorene derivatives were measured on a Pt-degrees electrode versus Ag-degrees/Ag+ in acetonitrile-TBAFB by cyclic voltammetry. The highest occupied molecular orbital (HOMO) energies of the compounds were calculated within the Huckel molecular orbital (HMO) framework. The measured E(p,a) values were correlated to theoretical HOMO energies with a linear regression model.