Preparation and Characterization of Polypropylene/Serpentine Composites

Date

2011-07-15

Author

Tan, Semra
Tincer, İsmail Teoman

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

223
views

0
downloads

Composites of serpentine and polypropylene (PP) were prepared by twin-screw extrusion. Serpentine was collected as rocks from the Ankara-Beynam region and ground into powder with an average particle size of about 3 mu m for composite production. Both as-received (rock) and powdered serpentine were characterized. A silane coupling agent (SCA), gamma-aminopropyl triethoxy silane, was used for the surface treatment of serpentine. Mechanical properties of the composites were measured in terms of impact strength, elastic modulus, stress at yield, stress at break, and percentage strain at break. The addition of serpentine was found to have a profound effect on the reinforcement of the PP matrix. Because of the stronger interactions at the interphase induced by SCA treatment, mechanical properties were improved further in comparison with the untreated composites. Similar thermal and morphological behaviors were recorded for the composites with and without surface treatment. Thermal studies showed an increase in both melting temperature and percentage crystallinity of the composites. Scanning electron microscopy analysis revealed that homogeneous distribution of filler was observed at low filler contents, but a certain extent of agglomeration was also seen at high filler loadings. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 846-854, 2011

Subject Keywords

Materials Chemistry, General Chemistry, Surfaces, Coatings and Films, Polymers and Plastics

URI

https://hdl.handle.net/11511/48060

Journal

JOURNAL OF APPLIED POLYMER SCIENCE

DOI

https://doi.org/10.1002/app.33604

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Kinetics of polyurethane formation between glycidyl azide polymer and a triisocyanate Keskin, S; Özkar, Saim (Wiley, 2001-07-25) Kinetics of the polyurethane formation between glycidyl azide polymer (GAP) and a polyisocyanate, Desmodur N-100, were studied in the bulk state by using quantitative FTIR spectroscopy. The reaction was followed by monitoring the change in intensity of the absorption band at 2270 cm-l for NCO stretching in the IR spectrum, and was shown to obey second-order kinetics up to 50% conversion. The activation parameters were obtained from the evaluation of kinetic data at different temperatures in the range of 50-...
Preparation and characterization of ultrahigh molecular weight polyethylene and polyisoprene solvent-cast blend films Akinay, AE; Tincer, T (Wiley, 1998-02-28) This study covers the preparation of noncrosslinked and crosslinked solvent-cast blend films of ultrahigh molecular weight polyethylene (UHMWPE) and polyisoprene rubber (PIR) and their mechanical, thermal, IR spectroscopic, and morphological characterizations. Solvent-cast films of polymer blends with 0, 10, 20, 35, 50, and 65% PIR composition were prepared by vigorous stirring from a hot decalin solution. The films were crosslinked chemically by using acetophenone as a crosslinking agent under UV radiation...
Thermal characterization of glycidyl azide polymer (GAP) and GAP-based binders for composite propellants Selim, K; Özkar, Saim; Yılmaz, Levent (Wiley, 2000-07-18) Differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) were used to investigate the thermal behavior of glycidyl azide polymer (GAP) and GAP-based binders, which are of potential interest for the development of high-performance energetic propellants. The glass transition temperature (T-g) and decomposition temperature (T-d) of pure GAP were found to be -45 and 242 degrees C, respectively. The energy released during decomposition (Delta H-d) was measured as 485 cal/g. The effect of th...
Synthesis and Characterization of a New Conducting Polymer Based on 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-phthalonitrile Yavuz, Arzu; Bezgin, Buket; Önal, Ahmet Muhtar (Wiley, 2009-12-05) A new conducting polymer was synthesized by electrochemical polymerization of 4-(2,5-di-2-thiophen-2-yl-pyrrol-1-yl)-2-phthalonitrile (SNS-PN). Electrochemical polymerization of SNS-PN was performed in acetonitrile/0.2M LiClO4 solvent/electrolyte couple. Characterizations of the resulting polymer P(SNS-PN) were carried out by cyclic voltammetry, UV-vis, and Fourier transform infrared (FTIR) spectroscopic techniques. Spectroelectrochemical studies revealed that P(SNS-PN) has an electronic band gap of 2.45 eV...
Effect of surface treatment on electrical conductivity of carbon black filled conductive polymer composites Koysuren, Ozcan; Yesil, Sertan; Bayram, Göknur (Wiley, 2007-06-05) Two different types of surface modifiers, 3-aminopropyltriethoxysilane and formamide, were applied to carbon black (CB) particles to lower electrical resistivity of polymer composites prepared by treated CB. Two different matrices, low-density polyethylene and nylon 6, were chosen to compound with surface modified CB. Surface energy of CB was increased by adding amine or amide functional groups during surface treatment of CB. According to electron spectroscopy for chemical analysis (ESCA), chemical modifica...

Citation Formats

S. Tan and İ. T. Tincer, “Preparation and Characterization of Polypropylene/Serpentine Composites,” JOURNAL OF APPLIED POLYMER SCIENCE, pp. 846–854, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48060.