lntrazeolite Metal Carbonyl Kinetics: 12CO Substitution in Mo(12C0)6-Na56Y by PMe3 and 13CO

Özkar, Saim
The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the alpha-cage of the host lattice.


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Citation Formats
G. OZIN, S. Özkar, H. PASTORE, A. POE, and E. VICHI, “lntrazeolite Metal Carbonyl Kinetics: 12CO Substitution in Mo(12C0)6-Na56Y by PMe3 and 13CO,” JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, pp. 141–143, 1991, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48254.