INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13

Download
1991-02-01
OZIN, GA
Özkar, Saim
PASTORE, HO
POE, AJ
VICHI, EJS
The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the alpha-cage of the host lattice.

Citation Formats
G. OZIN, S. Özkar, H. PASTORE, A. POE, and E. VICHI, “INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13,” JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, no. 3, pp. 141–143, 1991, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48254.