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INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13
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Date
1991-02-01
Author
OZIN, GA
Özkar, Saim
PASTORE, HO
POE, AJ
VICHI, EJS
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the alpha-cage of the host lattice.
Subject Keywords
Molecular Medicine
URI
https://hdl.handle.net/11511/48254
Journal
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
DOI
https://doi.org/10.1039/c39910000141
Collections
Department of Chemistry, Article