INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13

Date

1991-02-01

Author

OZIN, GA
Özkar, Saim
PASTORE, HO
POE, AJ
VICHI, EJS

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The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the alpha-cage of the host lattice.

Subject Keywords

Molecular Medicine

URI

https://hdl.handle.net/11511/48254

Collections

Department of Chemistry, Article