Multipurpose selenophene containing conjugated polymers for optoelectronic applications

Date

2017-03-04

Author

ONK, Ipek
HIZALAN, Gonul
CEVHER, ŞEVKİ CAN
HACIOGLU, Serife O.
Toppare, Levent Kamil
Çırpan, Ali

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In this study, two new conjugated polymers were synthesized including benzotriazole (BTz) as the acceptor unit and selenophene as the bridge donor segment. These acceptors were coupled with fluorene and carbazole via Suzuki condensation reactions. Electrochemical band gaps were calculated as 2.45 eV for P1 and 2.40 eV for P2. Electrochemical and optical studies of polymers indicate that both polymers are promising candidates for organic solar cell (OSC) and polymer organic light emitting diode (PLED) applications since they have suitable HOMO-LUMO energy levels and appropriate absorption and emission band ranges. Light emitting properties of synthesized polymers were investigated and the highest luminance value was found as 6608 cd/m(2) for P1 at 8V. Photovoltaic properties of polymers were investigated and the optimized device based on P2 showed 1.75% power conversion efficiency for P2 under AM 1.5 G illumination at 100 mW/cm(2).

Subject Keywords

Materials Chemistry, General Chemistry, Polymers and Plastics, Ceramics and Composites

URI

https://hdl.handle.net/11511/48390

Journal

Journal of Macromolecular Science, Part A: Pure and Applied Chemistry

DOI

https://doi.org/10.1080/10601325.2017.1265396

Collections

Department of Chemistry, Article

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Citation Formats

I. ONK, G. HIZALAN, Ş. C. CEVHER, S. O. HACIOGLU, L. K. Toppare, and A. Çırpan, “Multipurpose selenophene containing conjugated polymers for optoelectronic applications,” Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, pp. 133–139, 2017, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48390.