Crystallization field and rate study for the formation of single phase sodium-potassium and potassium clinoptilolite

Date

2011-04-01

Author

Guvenir, O.
Kalıpçılar, Halil
Culfaz, A.

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

187
views

0
downloads

Reproducible synthesis of clinoptilolite as the single crystalline phase was achieved in the narrow crystallization field at or around the nominal batch composition of 2.1(Na2O+K2O):Al2O3:10SiO(2):110H(2)O at 140 degrees C. Clinoptilolites of high purity were crystallized in the pure sodium or mixed sodium-potassium cation systems. Partial replacement of hydroxyl anions with the salts of carbonates or chlorides also yielded clinoptilolite as the single crystalline phase although at lower crystallization rates. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Subject Keywords

General Materials Science, General Chemistry, Condensed Matter Physics

URI

https://hdl.handle.net/11511/48512

Journal

CRYSTAL RESEARCH AND TECHNOLOGY

DOI

https://doi.org/10.1002/crat.201000513

Collections

Department of Chemical Engineering, Article

Suggestions

OpenMETU
Core

Crystallization of silicalite-1 from clear synthesis solutions: Effect of template concentration on crystallization rate and crystal size Soydas, B.; Çulfaz Emecen, Pınar Zeynep; Kalıpçılar, Halil; Culfaz, A. (Wiley, 2009-08-01) Synthesis of silicalite-1 powders and membranes from initially clear solutions with different tetrapropylammonium hydroxide or bromide concentrations was studied. While tetrapropylammonium bromide acts only as template, tetrapropylammonium hydroxide provides both the template and hydroxyl ions to the synthesis medium. The effects of template and hydroxyl ion concentration on the product yield, crystallization rate and crystal size were investigated. Pure and highly crystalline silicalite-1 was obtained with...
Crystallization field study for the formation of single phase sodium clinoptilolite: Batch composition, seed and temperature effects Guevenir, O.; Kalıpçılar, Halil; Culfaz, A. (Wiley, 2009-03-01) Although clinoptilolite is the most abundant zeolite mineral in nature, its synthesis under laboratory conditions has been difficult. A partial crystallization field study was done for the synthesis of clinoptilolite based on a nominal batch composition of 2.1Na(2)O:Al2O3:10Si(2)O:110H(2)O to delineate the limits of composition and temperature within which sodium clinoptilolite can be produced as a single phase in high yields. Effects of temperature, SiO2/Al2O3 molar ratio in the batch composition, and the ...
Synthesis and characterization of a new soluble conducting polymer and its electrochromic device Varis, Serhat; Ak, Metin; Tanyeli, Cihangir; Akhmedov, Idris Mecidoglu; Toppare, Levent Kamil (Elsevier BV, 2006-12-01) A mixture of isomers 2,5-di(4-methyl-thiophen-2-yl)-1-(4-nitrophenyl)-1H-pyrrole, 2-(4-methyl-thiophen-2-yl)-5-(3-methyl-thiophen-2-yl)1-(4-nitrophenyl)-1H-pyrrole and 2,5-di(3-methyl-thiophen-2-yl)-1-(4-nitrophenyl)-1H-pyrrole (Me-SNS(NO2)) were synthesized. Resulting monomers were polymerized chemically, producing soluble polymers in common organic solvents. The average molecular weight has been determined by gel permeation chromatography (GPC) as Mn = 5.6 x 10(3) for the chemically synthesized polymer. T...
Synthesis, crystal structure and characterization of new transition metal compounds of bromophenols: Bis(2,4,6-tribromophenolato) di(N-methylimidazole)M(II) (M=Co, Cu) Camurlu, P; Yılmaz, Ayşen; Tatar, L; Kisakurek, D; Ulku, D (Wiley, 2005-03-01) Bis(2,4,6-tribromophenolato)di(N-methyl imidazole)M(II), where M stands for cobalt and copper metals, was synthesized via reaction of the corresponding metal sulphate and 2,4,6-tribromophenolate in aqueous media in the presence of N-methyl imidazole and sodium hydroxide. Although various crystallization procedures were applied only cobalt complex was obtained as single crystals. The Co(II) ion has a distorted octahedral enviroment involving two O atoms and two N atoms of the Bis(2,4,6-tribromopbenolato)di(N...
Synthesis of submicron silicalite-1 crystals from clear solutions Kalıpçılar, Halil (Wiley, 2000-01-01) Discrete and monodisperse submicron crystals of silicalite-l with a mean size of 0.3 mum were synthesized from clear crystallization solutions. The effects of silica content, alkalinity of batch and the nature of silica source on the product yield, crystal morphology and particle size distribution were investigated. The crystal shape was sphere-like or hexagonal twinned disks when silicic acid was the silica source. Change of silica source to sodium silicate solution leads to the formation of rounded-edged-...

Citation Formats

O. Guvenir, H. Kalıpçılar, and A. Culfaz, “Crystallization field and rate study for the formation of single phase sodium-potassium and potassium clinoptilolite,” CRYSTAL RESEARCH AND TECHNOLOGY, pp. 345–350, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48512.