[MU-BIS(DIALKYLPHOSPHINO)ALKANE]-BIS[PENTACARBONYLMETAL(0)] COMPLEXES OF THE GROUP-6B ELEMENTS - SYNTHESIS AND SPECTROSCOPIC STUDY

Date

1993-01-01

Author

OZER, Z
Özkar, Saim
PAMUK, HO

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[mu-Bis(dialkylphosphino)alkane]-bis[pentacarbonylmetal(0)] complexes (CO)5MR2P(CH2)nPR2M(CO)5, (M: Cr, Mo, W; n: 1, 2, 3; R: CH3, C2H5, C6H5) were synthesized from the reaction of M(CO)5(CH3CN) with the appropriate ligand and characterized by means of IR and NMR (H-1, C-13, P-31) spectroscopy. Spectral data indicate that the complexes contain two identical M(CO)5 moieties linked to each other by the R2P(CH2)nPR2 ligand. Each metal atom has a pseudo-octahedral arrangement of the five CO ligands and one phosphorus atom.

Subject Keywords

General Chemistry

URI

https://hdl.handle.net/11511/48956

Journal

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES

DOI

https://doi.org/10.1515/znb-1993-0110

Collections

Department of Chemistry, Article

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Citation Formats

Z. OZER, S. Özkar, and H. PAMUK, “[MU-BIS(DIALKYLPHOSPHINO)ALKANE]-BIS[PENTACARBONYLMETAL(0)] COMPLEXES OF THE GROUP-6B ELEMENTS - SYNTHESIS AND SPECTROSCOPIC STUDY,” ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, pp. 37–43, 1993, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48956.