Synthesis of ferrocene substituted pyrrolidine derivatives via Et2Zn catalyzed 1 3 dipolar cycloaddition reactions of azomethine ylides

Date

2001-05-01

Author

Doğan, Özdemir

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Synthesis of ferrocene substituted pyrrolidine derivatives via diethylzinc catalyzed 1,3-dipolar cycloadditions of azomethine ylides is described. Azomethine ylides were generated from glycine methyl ester and ferrocenecarboxaldehyde by the 'imine tautomerization' method and trapped with dipolarophiles to give the corresponding cycloadducts in reasonable yields and high regio- and stereoselectivity.

Subject Keywords

Ferrocene, Pyrrolidine, Diethylzinc catalysis, 1,3-dipolar cycloadditions

URI

https://hdl.handle.net/11511/49145

Journal

Journal Of Organometallic Chemistry

DOI

https://doi.org/10.1016/s0022-328x(01)01034-8

Collections

Department of Chemistry, Article

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Citation Formats

Ö. Doğan, “Synthesis of ferrocene substituted pyrrolidine derivatives via Et2Zn catalyzed 1 3 dipolar cycloaddition reactions of azomethine ylides,” Journal Of Organometallic Chemistry, pp. 135–138, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/49145.