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Radiation-induced solid-state copolymerization in binary acrylamide-maleic anhydride systems
Date
1990-5
Author
Nugay, T.
Küçükyavuz, S.
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γ-Ray-initiated copolymerization of acrylamide and maleic anhydride was studied in the solid state at 25°C. The polymeric product was found to be free of the homopolymers. The mole fraction of acrylamide in the monomer mixture was varied from 0.33 to 0.91. The copolymerization reached a ‘limiting conversion’ the value of which was dependent on the composition of the monomer feed. The mole fraction of maleic anhydride in the copolymers did not exceed 0.50 and the compositions of copolymers obtained from acrylamide-rich mixtures were virtually the same as those from the monomer feed compositions. The alternating tendency of maleic anhydride was evidenced by the variation of the copolymer compositions and the consumption rates of the individual monomers.
Subject Keywords
Organic Chemistry
,
Polymers and Plastics
URI
https://hdl.handle.net/11511/51387
Journal
Polymer
DOI
https://doi.org/10.1016/0032-3861(90)90064-6
Collections
Department of Chemistry, Article
Citation Formats
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MLA
BibTeX
T. Nugay and S. Küçükyavuz, “Radiation-induced solid-state copolymerization in binary acrylamide-maleic anhydride systems,”
Polymer
, vol. 31, no. 5, pp. 958–960, 1990, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51387.