POLYMERIZATION OF 1-ETHYNYL-1-CYCLOHEXANOL BY RADIATION, ELECTROINITIATION, AND CHEMICAL CATALYSTS

Date

1992-01-01

Author

Usanmaz, Ali
KIZILIRMAK, N

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Solid-state polymerization of 1-ethynyl-1-cyclohexanol was carried out by irradiation in vacuum and in open air at 20-degrees-C. Radiation-induced polymerization was also done in a benzene solution. The products were mixtures of oligomers and polymers. IR, NMR, UV, and x-ray investigations showed the initial formation of trimer, oligomer, and polymer. The polymer fraction increased with an increase of conversion. Electroinitiated polymerization gave soluble and insoluble fractions. The soluble fraction was an ether. However, the results were not reproducible. No polymers were obtained with n-butyllithium and borontrifluoride etherate as chemical catalysts.

Subject Keywords

Materials Chemistry, General Chemistry, Polymers and Plastics, Ceramics and Composites

URI

https://hdl.handle.net/11511/52127

Journal

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY

DOI

https://doi.org/10.1080/10601329208054149

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

A. Usanmaz and N. KIZILIRMAK, “POLYMERIZATION OF 1-ETHYNYL-1-CYCLOHEXANOL BY RADIATION, ELECTROINITIATION, AND CHEMICAL CATALYSTS,” JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, pp. 1175–1185, 1992, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/52127.