CCL- and PLE-catalyzed reverse enantiomeric separation of various (+/-)-2-thienylcarbinols

Date

2001-01-01

Author

Tanyeli, Cihangir
Ozdemirhan, D

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(+/-)-2-Thienylcarbinols and their O-acetyl derivatives were resolved in reverse separation by CCL and PLE catalysed hydrolysis to afford optically active 2-thienylcarbinols in 35%-99% e.e. that are valuable chiral building blocks, in particular in the synthesis of pheromones and some alkoloid type natural products. Absolute configurations were determined by the correlation of specific rotation values with the literature and by transforming into the corresponding secondary alcohols via reductive desulfurization by Ra-Ni.

Subject Keywords

CCL, PLE, Reductive desulfurization, 2-thienylcarbinols

URI

https://hdl.handle.net/11511/54518

Journal

ENANTIOMER

Collections

Department of Chemistry, Article

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Citation Formats

C. Tanyeli and D. Ozdemirhan, “CCL- and PLE-catalyzed reverse enantiomeric separation of various (+/-)-2-thienylcarbinols,” ENANTIOMER, pp. 259–265, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/54518.