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Reinvestigation of the synthetic and mechanistic aspects of Mn(III) acetate mediated oxidation of enones

2004-04-05
Demir, Ayhan Sıtkı
Reis, O
Igdir, AC
Mn(OAc)(3) mediated alpha'-acetoxylation of alpha,beta-unsaturated enones is reinvestigated from a synthetic and mechanistic point of view and an improved procedure based on the use of acetic acid as a co-solvent is presented. Excellent results were obtained for a variety of structurally diverse and synthetically important enones under the optimized conditions.