Reinvestigation of the synthetic and mechanistic aspects of Mn(III) acetate mediated oxidation of enones

Date

2004-04-05

Author

Demir, Ayhan Sıtkı
Reis, O
Igdir, AC

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Mn(OAc)(3) mediated alpha'-acetoxylation of alpha,beta-unsaturated enones is reinvestigated from a synthetic and mechanistic point of view and an improved procedure based on the use of acetic acid as a co-solvent is presented. Excellent results were obtained for a variety of structurally diverse and synthetically important enones under the optimized conditions.

Subject Keywords

Organic Chemistry, Biochemistry, Drug Discovery

URI

https://hdl.handle.net/11511/56762

Journal

TETRAHEDRON

DOI

https://doi.org/10.1016/j.tet.2004.02.039

Collections

Department of Chemistry, Article

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Citation Formats

A. S. Demir, O. Reis, and A. Igdir, “Reinvestigation of the synthetic and mechanistic aspects of Mn(III) acetate mediated oxidation of enones,” TETRAHEDRON, pp. 3427–3432, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56762.