Generation of aryl radicals from arylboronic acids by manganese(III) acetate: Synthesis of biaryls and heterobiaryls

Date

2003-01-24

Author

Demir, Ayhan Sıtkı
Reis, O
Emrullahoglu, M

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The efficient generation of aryl radicals from arylboronic acids by manganese(III) acetate is described. In aromatic solvents, in situ generated aryl radicals afford the corresponding biaryls in very good yields. This method works selectively, and yields are better than those from similar, previously described methods. Arylboronic acids carrying sensitive functional groups also work efficiently.

Subject Keywords

Thiophenes, Hydrocarbons, Lipids, Aromatic compounds, Organic compounds

URI

https://hdl.handle.net/11511/58029

Collections

Department of Chemistry, Article