Synthesis and characterizations of N,N,N ',N '-tetrakis (diphenylphosphino)ethylendiamine derivatives: Use of palladium(II) complex as pre-catalyst in Suzuki coupling and Heck reactions

2009-03-01
AKBA, OSMAN
DURAP, FEYYAZ
AYDEMİR, MURAT
BAYSAL, AKIN
Guemguem, Bahattin
Özkar, Saim
Oxidation of N,N,N',N'-tetrakis(diphenylphosphino)ethylendiamine (1) with elemental sulfur and selenium gives the corresponding sulfide and selenide, respectively, [(Ph2P(E))(2)NCH2CH2N(P(E)Ph-2)(2)] (E: S 1a, Se 1b). Complexes of 1 [(M2Cl4){(Ph2P)(2)NCH2CH2N(PPh2)(2)}] (M: Ni(II) 1c, Pd(II) 1d, Pt(II) 1e) were prepared by the reaction of 1 with NiCl2 or [MCl2(COD)] (M = Pd, Pt). The new compounds were characterized by NMR, IR spectroscopy and elemental analysis. The catalytic activity of Pd(II) complex 1d was tested in the Suzuki coupling reaction and Heck reaction. The palladium complex 1d catalyses the Heck reaction between styrene and aryl bromides as well as Suzuki coupling reaction between phenylboronic acid and arylbromides affording stilbenes and biphenyls in high yield, respectively.
JOURNAL OF ORGANOMETALLIC CHEMISTRY

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Citation Formats
O. AKBA, F. DURAP, M. AYDEMİR, A. BAYSAL, B. Guemguem, and S. Özkar, “Synthesis and characterizations of N,N,N ‘,N ’-tetrakis (diphenylphosphino)ethylendiamine derivatives: Use of palladium(II) complex as pre-catalyst in Suzuki coupling and Heck reactions,” JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp. 731–736, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/63005.