Thermal polymerization of bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex in solution and in solid state

Date

1998-02-01

Author

Kisakurek, D
Akbas, M
Bilir, N

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The synthesis of the bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex was achieved from aqueous solution, and its characterization was performed by means-of IR and CHN elemental analysis. Thermal polymerization of this complex was carried out in toluene and in solid state. The structural analysis of the polymers was performed with H-1 NMR, C-13 NMR and FTIR analysis; the glass transition temperature was found to be at 160 degrees C. 4-Fluoro-2,6-dibromophenolate, with the non-chelating ligand pyridine, displays selectivity in favor of 1,2-catenation.

Subject Keywords

Physical and Theoretical Chemistry, Organic Chemistry, Materials Chemistry, Polymers and Plastics, Condensed Matter Physics

URI

https://hdl.handle.net/11511/66350

Journal

MACROMOLECULAR CHEMISTRY AND PHYSICS

DOI

https://doi.org/10.1002/macp.1998.021990202

Collections

Department of Chemistry, Article

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Citation Formats

D. Kisakurek, M. Akbas, and N. Bilir, “Thermal polymerization of bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex in solution and in solid state,” MACROMOLECULAR CHEMISTRY AND PHYSICS, pp. 169–173, 1998, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/66350.