Polymerisation of bis(trichlorophenolato)tri(pyridine)nickel and bis (trihalophenolato)di(pyridine)nickel (II) complexes in solid state

Date

2000-06-01

Author

Kisakurek, D
Aslan, A
Isci, H

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The synthesis of five-coordinated bis(trihalophenolato)tri (pyridine)nickel (II) and four-coordinated his (trihalophenolato)di(pyridine) nickel(II) complexes from an aqueous solution and their characterisation by FT-IR, X-ray, DSC and elemental analysis is described. The thermal polymerisation of these complexes was carried out in the solid state and in the melt. Structural analyses were performed using H-1 NMRI C-13 NMR and FT-IR spectroscopic analyses. T(g)s were determined by differential thermal analysis and the molecular weights by viscometric method.

Subject Keywords

Bis(trihalophenolato)tri(pyridine)nickel(II), Bis(trihalophenolato)di(pyridine)nickel(II), Solid state thermal polymerisation

URI

https://hdl.handle.net/11511/66974

Journal

POLYMER

DOI

https://doi.org/10.1016/s0032-3861(99)00749-1

Collections

Department of Chemistry, Article

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Citation Formats

D. Kisakurek, A. Aslan, and H. Isci, “Polymerisation of bis(trichlorophenolato)tri(pyridine)nickel and bis (trihalophenolato)di(pyridine)nickel (II) complexes in solid state,” POLYMER, pp. 5149–5155, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/66974.