Efficient synthesis of 1-alkoxycarbonyl-methyl-2-alkylpyrroles from dichloro- and methoxychloropropylalkyl ketones

Gadzhili, RA
Nadzhafova, RA
Sesenoglu, O
The condensation reaction of 2,3-dichloropropyl- and 2-methoxy-3-chloropropyl alkyl ketones with alkyl 2-aminoacetate salts leads to 1-alkoxy-carbonylmethyl-2-alkylpyrroles. These compounds, with various bases, gave 1-carbamoylmethyl-, 1-dialkylaminocarbonylmethyl-, 1-carbazoyl methyl-2-alkylpyrroles and potassium salt of 2-alkyl-pyrrolyl-1-acetic acid.


Synthesis of n-(2-propylphenyl) substituted chiral amino alcohols and their usage in enantioselective diethylzinc addition reactions
Günler, Zeynep İnci; Tanyeli, Cihangir; Department of Chemistry (2011)
IChiral 1,2-amino alcohols were synthesized via newly developed “intramolecular unsaturation transfer” using cyclohexanone, propargyl bromide, and various chiral amino alcohols as starting components. These amino alcohols can be potential chiral ligands for many asymmetric transformation reactions. Therefore, their effectiveness as chiral ligands in diethylzinc addition to benzaldehyde and N-diphenylphosphinoyl imines were tested. Various parameters including temperature, solvent, ligand amount etc. were sc...
Efficient rearrangement of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)(6)(H2O)(3)]
Erturk, Erkan; Gollu, Mehmet; Demir, Ayhan Sıtkı (Elsevier BV, 2010-03-27)
The mixed-valent oxo-centered triiron(III, III, II) trifluoroacetate complex [(Fe2FeO)-Fe-III-O-II(C2CCF3)(6)(H2O)(3)] Was prepared by reacting anhydrous iron(III) chloride with boiling trifluoroaceric acid under nitrogen. The non-hygroscopic and readily available mixed-valent triiron trifluoroacetate complex Was found to be an efficient catalyst for the regioselective rearrangement of epoxides. A number of carbonyl compounds formed via the rearrangement of epoxides could be obtained by a simple filtration ...
Efficient Acetylation of Xylans by Exploiting the Potassium Acetate Formed During the Alkaline Extraction
AKKUS, Merve; Özkan, Necati; BAKIR, Ufuk (2018-08-01)
Isolation of hemicelluloses through alkaline extraction results in formation of salts, which usually necessitates additional salt removal steps. In this study, acetylation of xylans was studied without the removal of potassium acetate (KAc), a commonly produced salt during the alkaline extraction, to find a facile method to alter the hydrophilic characteristics of hemicelluloses. The acetylation reaction was carried out solely with acetic anhydride without any catalysts or solvents added. The weight gain an...
Measurement of transport properties of poly(methylmethacrylate-co-methacrylic acid) ion-containing membranes
Şanli, Oya; Aras, Leyla (Wiley, 1990)
Several membranes prepared from poly(methylmethacrylate‐co‐methacrylic acid) and its Li+ and Zn2+ ionomers were tested for NaCl, creatinine and urea permeability. The permeabilities of the membranes were explained on the basis of pore contents determined from their scanning electron microscope micrographs. All the membranes showed higher permeabilities during the first 2 hours of experimentation. Introduction of Zn2+ ions into the copolymer as crosslinking agent did not have much effect on the membrane prop...
Carbas, Buket Bezgin; Odabas, Serhat; Turksoy, Figen; Tanyeli, Cihangir (2016-03-01)
Poly-1,1,2,2-tetrakis(4-9H-carbazol-9-yl)phenyl)ethene P(TCP) was successfully synthesized by electrochemical oxidation of corresponding monomer, namely, 1,1,2,2-tetrakis(4-9H-carbazol-9-yl)phenyl)ethene (TCP) using dichloromethane as the solvent and tetrabutylammonium hexafluorophosphate (TBAPF(6)) as supporting electrolyte. Spectroelectrochemical properties of P(TCP) were investigated in situ recording the electronic absorption spectra of the polymer film coated on indium-tin oxide (ITO) at various potent...
Citation Formats
R. Gadzhili, R. Nadzhafova, and O. Sesenoglu, “Efficient synthesis of 1-alkoxycarbonyl-methyl-2-alkylpyrroles from dichloro- and methoxychloropropylalkyl ketones,” TURKISH JOURNAL OF CHEMISTRY, pp. 379–383, 2002, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/67064.