Compatibilization of poly(2,6-dimethyl-1,4-phenylene oxide) and poly(2,6-dichloro-1,4-phenylene oxide) with sulfonated polystyrene and its Na and Zn-neutralized ionomers

Date

2003-05-01

Author

Mih, M
Aras, L
Alkan, C

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Compatibility of acidic (H), Na, and Zn neutralized sulfonated polystyrene ionomer blends with Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and Poly(2,6-dichloro-1,4-phenylene oxide) (PDCIPO) was investigated by Dilute Solution Viscometry (DSV) and Differential Scanning Calorimetry (DSC). The intrinsic viscosities of the blends, are measured in suitable solvents. The degree of compatibility of the blends is characterized by Ab parameter. According to the results, PPO is completely miscible, except for Na-neutralized 1.7 mol% sulfonated polystyrene (Na1.7SPS) which is completely immiscible with PPO and PDClPO. PDCIPO is completely miscible with Zn-neutralized sulfonated polystyrene (Zn4.8SPS) and partially miscible with acid sulfonated polystyrene (4.8SPS).

Subject Keywords

Materials Chemistry, General Chemistry, Polymers and Plastics, Condensed Matter Physics

URI

https://hdl.handle.net/11511/67096

Journal

POLYMER BULLETIN

DOI

https://doi.org/10.1007/s00289-003-0150-3

Collections

Department of Chemistry, Article

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Citation Formats

M. Mih, L. Aras, and C. Alkan, “Compatibilization of poly(2,6-dimethyl-1,4-phenylene oxide) and poly(2,6-dichloro-1,4-phenylene oxide) with sulfonated polystyrene and its Na and Zn-neutralized ionomers,” POLYMER BULLETIN, pp. 191–196, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/67096.