Show/Hide Menu
Hide/Show Apps
anonymousUser
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Videos
Videos
Thesis submission
Thesis submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Contact us
Contact us
PHOTOCHEMICAL-REACTIONS OF TRANSITION METAL-OLEFIN COMPLEXES .11. [4+6]-CYCLOADDITION OF TRICYCLO[6.3.0.0(2.7)]UNDECA-3,5-DIENE IN TRICARBONYL-ETA-6-1,3,5-CYCLOHEPTATRIENE-CHROMIUM(0)
Date
1985-01-01
Author
Özkar, Saim
KREITER, CG
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
2
views
0
downloads
Cite This
The photochemical reaction of tricarbonyl-η6-1,3,5-cycloheptatriene-chromium(0) (I) with tricyclo[6.3.0.02,7]undeca-3,5-diene (II) in n-pentane at 248 K yields the [4 + 6]-cycloadduct tricarbonyl-η6-pentacyclo[7.6.2.110,15.02,8.03,7]octadeca-11,13,16-triene-chromium(0) (III). Detachment of the pentacyclic triene ligand from chromium can be achieved with trimethylphosphite. The constitutions of complex III and of the pentacyclic hydrocarbon IV were determined by spectroscopic means.
Subject Keywords
Physical and Theoretical Chemistry
,
Inorganic Chemistry
,
Organic Chemistry
,
Materials Chemistry
,
Biochemistry
URI
https://hdl.handle.net/11511/69981
Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
DOI
https://doi.org/10.1016/0022-328x(85)80292-8
Collections
Department of Chemistry, Article
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
S. Özkar and C. KREITER, “PHOTOCHEMICAL-REACTIONS OF TRANSITION METAL-OLEFIN COMPLEXES .11. [4+6]-CYCLOADDITION OF TRICYCLO[6.3.0.0(2.7)]UNDECA-3,5-DIENE IN TRICARBONYL-ETA-6-1,3,5-CYCLOHEPTATRIENE-CHROMIUM(0),”
JOURNAL OF ORGANOMETALLIC CHEMISTRY
, vol. 293, no. 2, pp. 229–233, 1985, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/69981.