PHOTOCHEMICAL-REACTIONS OF TRANSITION METAL-OLEFIN COMPLEXES .11. [4+6]-CYCLOADDITION OF TRICYCLO[6.3.0.0(2.7)]UNDECA-3,5-DIENE IN TRICARBONYL-ETA-6-1,3,5-CYCLOHEPTATRIENE-CHROMIUM(0)

Date

1985-01-01

Author

Özkar, Saim
KREITER, CG

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

1
views

0
downloads

The photochemical reaction of tricarbonyl-η6-1,3,5-cycloheptatriene-chromium(0) (I) with tricyclo[6.3.0.02,7]undeca-3,5-diene (II) in n-pentane at 248 K yields the [4 + 6]-cycloadduct tricarbonyl-η6-pentacyclo[7.6.2.110,15.02,8.03,7]octadeca-11,13,16-triene-chromium(0) (III). Detachment of the pentacyclic triene ligand from chromium can be achieved with trimethylphosphite. The constitutions of complex III and of the pentacyclic hydrocarbon IV were determined by spectroscopic means.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Materials Chemistry, Biochemistry

URI

https://hdl.handle.net/11511/69981

Collections

Department of Chemistry, Article