Electroinitiated polymerization of bis (trihalophenoxo) ethylenediamine copper (II) complexes.

Yiğit, Semih


Electroinitiated polymerization of 2-allylphenol
Cihaner, A; Önal, Ahmet Muhtar (2000-08-01)
Redox behaviour of 2-allylphenol (2APhOH) was studied by using cyclic voltammetry (CV) and electroinitiated polymerization was conducted at the measured peak potentials. Constant potential electrolysis (CPE) of the monomer was carried out in acetonitrile-sodium perchlorate, solvent-electrolyte couple, at room temperature. Polymerization of the monomer yielded insoluble polymer films on the surface of the electrode together with the low molecular weight polymers in the bulk of the solution. The structural an...
YURTTAS, B; Toppare, Levent Kamil; Akbulut, Ural (Informa UK Limited, 1988-01-01)
Anionic polymerization of acrylonitrile was achieved by constant-potential electrolysis via direct electron transfer to the monomer. The reduction peak potential in the (C4 H9)4 NBF4 -CH3 CN electrolyte-solvent system was measured by cyclic voltammetry. On the other hand, dimethylformamide-metal salts were not found suitable for the direct electron-transfer process in our system. Polymers produced both anodically and cathodically were found to contain cyclized structures.
Electroinitiated polymerization of bis(pyrinide)bis (trihalophenolato)nickel (II)complexes
Aydeniz, Keziban; Kısakürek, Duygu; Önal, Ahmet M.; Department of Chemistry (1999)
AYBAR, SP; HACIOGLU, B; Akbulut, Ural (1991-12-01)
Electroinitiated polymerization of butadiene sulfone was achieved by direct electron transfer in acetonitrile-tetrabutylammonium fluoroborate system by controlled potential electrolysis technique. High conversions were obtained at reasonable temperatures and polymerization times. The polymer was found to be composed of linear segments along with some cyclic units. The effect of monomer concentration, temperature, and polymerization potential on the rate of polymerization was investigated. Temperature an...
Electroinitiated polymerization of butadiene sulfone
Aybar, Selçuk Pınar; Akbulut, Ural; Department of Chemistry (1989)
Citation Formats
S. Yiğit, “Electroinitiated polymerization of bis (trihalophenoxo) ethylenediamine copper (II) complexes.,” Middle East Technical University, 1988.