Electroinitiated polymerization of butadiene sulfone

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1989
Aybar, Selçuk Pınar
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https://hdl.handle.net/11511/8743
Graduate School of Natural and Applied Sciences, Thesis

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ELECTROINITIATED POLYMERIZATION OF BUTADIENE SULFONE
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Electroinitiated polymerization of butadiene sulfone was achieved by direct electron transfer in acetonitrile-tetrabutylammonium fluoroborate system by controlled potential electrolysis technique. High conversions were obtained at reasonable temperatures and polymerization times. The polymer was found to be composed of linear segments along with some cyclic units. The effect of monomer concentration, temperature, and polymerization potential on the rate of polymerization was investigated. Temperature an...
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Anionic polymerization of acrylonitrile was achieved by constant-potential electrolysis via direct electron transfer to the monomer. The reduction peak potential in the (C4 H9)4 NBF4 -CH3 CN electrolyte-solvent system was measured by cyclic voltammetry. On the other hand, dimethylformamide-metal salts were not found suitable for the direct electron-transfer process in our system. Polymers produced both anodically and cathodically were found to contain cyclized structures.
ELECTROINITIATED POLYMERIZATION OF ACRYLAMIDE BY DIRECT ELECTRON-TRANSFER
HACIOGLU, B; Akbulut, Ural; Toppare, Levent Kamil (Wiley, 1989-10-01)
Electroinitiated polymerization of acrylamide was carried out in acetonitrile–tetrabutylammonium fluoroborate by electrolytic reduction of monomer. It was shown by cyclic voltammetry that direct electron transfer from the cathode to the monomer can be achieved in this solvent–electrolyte system. Reduction peak potentials measured by cyclic voltammetry indicated that sodium salts will interfere with such a mechanism. Since the reduction peak potential of sodium salt and dimethylformamide are found to be lowe...
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Citation Formats
S. P. Aybar, “Electroinitiated polymerization of butadiene sulfone,” Middle East Technical University, 1989.
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