Thermodynamic properties of 1 x MgCl2 xCaCl2 melts

Date

1986-01-01

Author

Karakaya, İshak

Metadata

Show full item record

Item Usage Stats

117
views

0
downloads

An electrochemical formation cell was used to measure the partial molar thermodynamic properties of MgCl2 in {(1−x)MgCl2 + xCaCl2}(1). The results indicate that the melt is nearly ideal in the Raoultian (or Temkin) sense. A classical-thermodynamics analysis of the results was used to construct the T(x) phase diagram which was found to be in good agreement with the accepted diagram.

URI

https://hdl.handle.net/11511/88373

Journal

J. Chemical Thermodynamics

DOI

https://doi.org/10.1016/0021-9614(86)90120-5

Collections

Department of Metallurgical and Materials Engineering, Article

Suggestions

OpenMETU
Core

Thermodynamic properties of SnO in SnO TiO2 melts Karakaya, İshak (1983-01-01) Oxygen concentration cells employing zirconia-calcia solid electrolytes were used to measure the thermodynamic properties of SnO in SnO-TiO2 melts and to redetermine the properties of pure-SnO and SnO2. Deviations from ideality in the melts were interpreted in terms of the existence of orthotitanate anions.
Thermodynamic properties of simple liquid metals calculated using an analytic pair potential Khajil, T. M. A.; Tomak, Mehmet (American Physical Society (APS), 1988-11-1) An analytic pair potential proposed by Pettifor and Ward is used to calculate the thermodynamic properties of Na, Mg, and Al. The energy, pressure, and bulk-modulus values calculated using the Pettifor-Ward pair potential are in qualitative accord with calculations based on other models.
THERMODYNAMIC PROPERTIES OF MGCL2-NACL MELTS FROM EMF-MEASUREMENTS Karakaya, İshak (The Electrochemical Society, 1986-04-01) A formation cell was used to study the thermodynamic properties associated with the formation of pure liquid and dissolved in binary melts. The data were used to infer the enthalpy and entropy of mixing. These measurements are shown to be consistent with the known phase diagram.
Rheological characterization of polyethylene glycol based TiO2 nanofluids YAPICI, KERİM; KEKLİKCİOĞLU ÇAKMAK, NEŞE; Ilhan, Naciye; Uludağ, Yusuf (2014-11-01) Rheological characterization of TiO2 nanoparticle dispersions in polyethylene glycol (PEG 200) is presented over 1-10 wt% particle mass fraction range in terms of shear viscosity, thixotropy and linear viscoelasticity. A stress controlled rheometer fitted by a cone-and-plate system was employed for the rheological measurements between -10 degrees C and 40 degrees C. The non-linear viscoelastic experiments revealed that TiO2-PEG 200 nanofluid exhibits a shear thinning behavior when particle mass fraction exc...
Thermo-Elastic and Lattice Dynamical Properties of Pd3X (X = Ti, Zr, Hf) Alloys: An Ab Initio Study Sürücü, Gökhan; Colakoglu, K.; ÇİFTCİ, YASEMİN; Ozisik, H. B.; Deligoz, E. (2015-12-01) Using the generalized-gradient approximation (GGA) based on density functional theory, we have reported the structural, mechanical, electronic, and lattice dynamical properties of the intermetallic compounds Pd3X (X = Ti, Zr, Hf) with D0(24) and the L1(2) structures. The elastic constants were predicted using the stress-finite strain technique. We performed numerical estimations of the bulk modulus, shear modulus, Young's modulus, Poisson's ratio anisotropy factor, G/B ratio, and hardness. Our studies have ...

Citation Formats

İ. Karakaya, “Thermodynamic properties of 1 x MgCl2 xCaCl2 melts,” J. Chemical Thermodynamics, pp. 859–866, 1986, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/88373.