Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Graphene oxide/magnesium oxide nanocomposite: A novel catalyst for ozonation of phenol from wastewater
Date
2017-01-01
Author
Heidarizad, Mahdi
Şengör, Sema Sevinç
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
160
views
0
downloads
Cite This
Catalytic ozonation is a promising advanced oxidation technique for the removal of contaminants from water and wastewater. Graphene oxide (GO) is an oxidized derivative of graphene which contains epoxide, hydroxyl, and carboxyl groups with high surface area, and is being recently used for effective adsorption of pollutants in aquatic environments. In our previous work, we modified GO with magnesium oxide (MgO) and demonstrated the high-rate adsorption of methylene blue (MB) by the synthesized nanocomposite (NC). In this study, our synthesized NC is applied as a catalyst for catalytic ozonation of phenol in a laboratory scale batch reactor. The results showed that the catalytic ozonation significantly improved the mineralization of phenol compared to that of ozonation without the catalyst. The impact of experimental variables on oxidation of phenol, particularly GO/MgO NC dosage and reaction time is investigated. A possible mechanism for the catalytic ozonation of phenol is also proposed. Our results show promising application of the proposed technology for the removal of various organic contaminants from wastewater.
URI
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85021412234&origin=inward
https://hdl.handle.net/11511/93659
DOI
https://doi.org/10.1061/9780784480595.018
Conference Name
17th World Environmental and Water Resources Congress 2017
Collections
Department of Environmental Engineering, Conference / Seminar
Suggestions
OpenMETU
Core
Diesel Oil Degradation Potential of a Bacterium Inhabiting Petroleum Hydrocarbon Contaminated Surface Waters and Characterization of Its Emulsification Ability
Onur, Gozde; Yılmaz, Fadime; İçgen, Bülent (Wiley, 2015-07-01)
Degradation of poorly water soluble hydrocarbons, like n-alkanes and polycyclic aromatic hydrocarbons are challenged by some bacteria through emulsification of hydrocarbons by producing biosurfactants. In diesel oil bioremediation, diesel oil degrading and surfactant producing bacteria are used to eliminate these pollutants from contaminated waters. Therefore, identifying and characterizing bacteria capable of producing surfactant and degrading diesel oil are pivotal. In this study, bacteria isolated from h...
Homogeneous and heterogeneous catalytic ozonation of pulp bleaching effluent
Balcioglu, Isil Akmehmet; Moral, Cigdem Kivilcimndan (2008-08-31)
Catalytic ozonation is a promising treatment method for both water and wastewater. In this study, in order to increase the biodegradability of bleaching wastewater from an integrated pulp- and -paper production plant, granulated activated carbon-(GAC), iron-(Fe2+) and manganese-(Mn2+) ion-catalyzed ozonation processes were used as a pre-treatment process. The effects of the catalyst concentration and the initial pH (pH(i)) of wastewater on the treatment efficiency of processes were investigated. Although me...
Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia-borane: High activity and long lifetime
DURAP, FEYYAZ; Zahmakiran, Mehmet; Özkar, Saim (2009-09-01)
The simplest amine-borane, considered as solid hydrogen storage material, ammonia-borane (H(3)NBH(3)) can release hydrogen gas upon catalytic hydrolysis under mild conditions. Herein, we report the preparation of a novel catalyst, water dispersible laurate-stabilized ruthenium(0) nanoclusters from the dimethylamine-borane reduction of ruthenium(III) chloride in sodium laurate solution at room temperature. The ruthenium nanoclusters in average size of 2.6 +/- 1.2 nm were isolated from the solution and well c...
Dihydroxylation of olefins catalyzed by zeolite-confined osmium(0) nanoclusters: an efficient and reusable method for the preparation of 1,2-cis-diols
Metin, Onder; Alp, Nurdan Alcan; Akbayrak, Serdar; Bicer, Abdullah; GÜLTEKİN, Mehmet Serdar; Özkar, Saim; Bozkaya, Ugur (2012-01-01)
Addressed herein is a novel, eco-friendly, recoverable, reusable and bottleable catalytic system developed for the dihydroxylation of various olefins yielding 1,2-cis-diols. In our protocol, zeolite-confined osmium (0) nanoclusters (zeolite-Os-0) are used as reusable catalyst and H2O2 served as a co-oxidant. Zeolite-Os-0 are found to be highly efficient and selective catalysts for the dihydroxylation of a wide range olefins in an aqueous acetone mixture at room temperature. In all of the olefins surveyed, t...
Surfactants as hydrate promoters?
Karaaslan, U; Parlaktuna, Mahmut (2000-09-01)
Natural gas hydrates from different types and concentrations of surfactant solutions were produced in a high-pressure cell. An anionic, a cationic, and a nonionic surfactant were used to prepare different concentration of surfactant solutions from deionized water. Although the thermodynamics of hydrate formation from a gas mixture is not affected with the existence of surfactants in the environment, there is an appreciable effect of type and concentration of surfactant on hydrate formation rate. The hydrate...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
M. Heidarizad and S. S. Şengör, “Graphene oxide/magnesium oxide nanocomposite: A novel catalyst for ozonation of phenol from wastewater,” presented at the 17th World Environmental and Water Resources Congress 2017, California, Amerika Birleşik Devletleri, 2017, Accessed: 00, 2021. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85021412234&origin=inward.