Dihydroxylation of olefins catalyzed by zeolite-confined osmium(0) nanoclusters: an efficient and reusable method for the preparation of 1,2-cis-diols

Date

2012-01-01

Author

Metin, Onder
Alp, Nurdan Alcan
Akbayrak, Serdar
Bicer, Abdullah
GÜLTEKİN, Mehmet Serdar
Özkar, Saim
Bozkaya, Ugur

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Addressed herein is a novel, eco-friendly, recoverable, reusable and bottleable catalytic system developed for the dihydroxylation of various olefins yielding 1,2-cis-diols. In our protocol, zeolite-confined osmium (0) nanoclusters (zeolite-Os-0) are used as reusable catalyst and H2O2 served as a co-oxidant. Zeolite-Os-0 are found to be highly efficient and selective catalysts for the dihydroxylation of a wide range olefins in an aqueous acetone mixture at room temperature. In all of the olefins surveyed, the catalytic dihydroxylation reaction proceeds smoothly and the corresponding 1,2-cis-diols are obtained in excellent chemical yield under the optimized conditions. The present heterogeneous catalyst system provides many advantages, such as being eco-friendly and industrially applicable over the traditional homogenous OsO4-NMO system for the dihydroxylation of olefins.

Subject Keywords

Asymmetric dihydroxylation, İon, Silica, Complex, Selective dihydroxylation, Tetraoxid, Hydroxylation, Recyclable Catalyst

URI

https://hdl.handle.net/11511/37472

Journal

GREEN CHEMISTRY

DOI

https://doi.org/10.1039/c2gc16616j

Collections

Department of Chemistry, Article

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Citation Formats

O. Metin et al., “Dihydroxylation of olefins catalyzed by zeolite-confined osmium(0) nanoclusters: an efficient and reusable method for the preparation of 1,2-cis-diols,” GREEN CHEMISTRY, pp. 1488–1492, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37472.