Studies On Dodecaborate Dianion And Carborate Anion Amination And Their Use In Stabilization Of Aryldiazonium Cations

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2022-2

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Ünver, Ozan

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Boron is one of the most interesting elements in the periodic table. Boron chemistry is not ordinary due to the bonding. The bonding in boron related compounds is classified as non-classical bonds. Due to the bonding nature of boron, boron clusters have interesting properties, i.e. weakly coordinating ability. With this in mind, in this thesis, dodecaborate dianion and carborate anion were synthesized. The synthesized boron cages were derivatized and were subjected to amination reactions with two different synthetic routes. These cages were also used to capture aryldiazonium cations as salts and these cations were introduced to the clusters. Moreover, captured aryldiazonium cations were subjected to hetero Diels-Alder reactions.

Subject Keywords

Dodecaborate, Carborate, Amination, Aryldiazonium cations

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https://hdl.handle.net/11511/96289

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Graduate School of Natural and Applied Sciences, Thesis

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Citation Formats

O. Ünver, “Studies On Dodecaborate Dianion And Carborate Anion Amination And Their Use In Stabilization Of Aryldiazonium Cations,” M.S. - Master of Science, Middle East Technical University, 2022.