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Thermal catalytic hydrosilation of conjugated dienes with triethysilane in the presence of tricarbonylarenemetal complexes (metal: chromium, molybdenum, tungsten)
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093192.pdf
Date
2000
Author
Rouzi, Pazilaiti
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https://hdl.handle.net/11511/2635
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Graduate School of Natural and Applied Sciences, Thesis
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The thermal catalytic hydrosilylation of 1,3-butadiene (1), trans-2-methyl-1, 3-pentadiene (2), 2,3-dimethyl-1,3-butadiene (3), and isoprene (4), with triethylsilane were studied in the presence of M(CO)(3) (o-xylene) (M = Cr, Mo, W) complexes in polar and nonpolar solvents such as tetrahydrofuran, hexane and toluene. Mo(CO)(3) (o-xylene) was found to be the only active catalyst for the hydrosilylation of 3 with triethylsilane, which gave 1-triethylsilyl-2,3-dimethyl-2-butene (3a), as hydrosilylated product...
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P. Rouzi, “Thermal catalytic hydrosilation of conjugated dienes with triethysilane in the presence of tricarbonylarenemetal complexes (metal: chromium, molybdenum, tungsten),” Middle East Technical University, 2000.