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Coupling of ferrocenyl chromium carbene complex with cyclobutenediones
Date
2002-08-15
Author
Zora, Metin
YÜCEL, Baris
Bekir Peynircioglu, N.
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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The coupling of ferrocenyl chromium carbene complex with cyclobutenediones leads to ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene-1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. The scope and limitations of these processes are investigated. In comparison with the phenyl analog, ferrocenyl chromium carbene complex has been found to be less reactive. This is also supported by PM3 calculations. The coupling of ferrocenyl chromium carbene complex with cyclobutenediones produces ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene-1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. In comparison with the phenyl analog, as supported by PM3 calculations, ferrocenyl chromium carbene complex has been found to be less reactive
Subject Keywords
Physical and Theoretical Chemistry
,
Inorganic Chemistry
,
Organic Chemistry
,
Materials Chemistry
,
Biochemistry
URI
https://hdl.handle.net/11511/34840
Journal
Journal of Organometallic Chemistry
DOI
https://doi.org/10.1016/s0022-328x(02)01403-1
Collections
Department of Chemistry, Article