Economic synthesis of quinaldinium fluorochromate(VI), (QnFC), and solvent-free periodic acid oxidation of alcohols catalyzed by QnFC

Date

2014-01-01

Author

Özdemir, Melek

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A 1: 1: 1 stoichiometric reaction between CrO3, aqueous HF, and quinaldine affords orange crystalline quinaldinium fluorochromate(VI) (QnFC) (C10H9NH[CrO3F]) in 99.4% isolated yield. A highly efficient, simple, chemoselective, and environmentally benign procedure for QnFC (3 mol%) catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones using 1.1 equiv of H5IO6 under solvent-free conditions is described.

Subject Keywords

General Chemistry

URI

https://hdl.handle.net/11511/35273

Journal

TURKISH JOURNAL OF CHEMISTRY

DOI

https://doi.org/10.3906/kim-1303-12

Collections

Department of Environmental Engineering, Article

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Citation Formats

M. Özdemir, “Economic synthesis of quinaldinium fluorochromate(VI), (QnFC), and solvent-free periodic acid oxidation of alcohols catalyzed by QnFC,” TURKISH JOURNAL OF CHEMISTRY, pp. 63–69, 2014, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35273.