PLE and HLE catalyzed reverse enantiomeric separation of (±)-methyl-2- methoxy-1-methyl-2,5-cyclohexadiene-1-carboxylate derivatives

Date

1999-03-26

Author

Tanyeli, Cihangir
Sezen, Bengu
Demir, Ayhan Sıtkı
ALVES, Rosemeire Brondi
ARSENİYADİS, Simeon

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We describe the diversities of hydrolase-type enzymes PLE and HLE on the hydrolysis of (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-1-carboxylate and (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-4-one-1-carboxylate to afford both enantiomers with 92-96% ee.

Subject Keywords

Organic-synthesis, Photorearrangement

URI

https://hdl.handle.net/11511/37386

Journal

Tetrahedron Asymmetry

DOI

https://doi.org/10.1016/s0957-4166(99)00080-4

Collections

Department of Chemistry, Article

Citation Formats

C. Tanyeli, B. Sezen, A. S. Demir, R. B. ALVES, and S. ARSENİYADİS, “PLE and HLE catalyzed reverse enantiomeric separation of (±)-methyl-2- methoxy-1-methyl-2,5-cyclohexadiene-1-carboxylate derivatives,” Tetrahedron Asymmetry, vol. 10, no. 6, pp. 1129–1133, 1999, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37386.