PLE and HLE catalyzed reverse enantiomeric separation of (±)-methyl-2- methoxy-1-methyl-2,5-cyclohexadiene-1-carboxylate derivatives

Date

1999-03-26

Author

Tanyeli, Cihangir
Sezen, Bengu
Demir, Ayhan Sıtkı
ALVES, Rosemeire Brondi
ARSENİYADİS, Simeon

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

5
views

0
downloads

We describe the diversities of hydrolase-type enzymes PLE and HLE on the hydrolysis of (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-1-carboxylate and (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-4-one-1-carboxylate to afford both enantiomers with 92-96% ee.

Subject Keywords

Organic-synthesis, Photorearrangement

URI

https://hdl.handle.net/11511/37386

Collections

Department of Chemistry, Article