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PLE and HLE catalyzed reverse enantiomeric separation of (±)-methyl-2- methoxy-1-methyl-2,5-cyclohexadiene-1-carboxylate derivatives
Date
1999-03-26
Author
Tanyeli, Cihangir
Sezen, Bengu
Demir, Ayhan Sıtkı
ALVES, Rosemeire Brondi
ARSENİYADİS, Simeon
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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We describe the diversities of hydrolase-type enzymes PLE and HLE on the hydrolysis of (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-1-carboxylate and (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-4-one-1-carboxylate to afford both enantiomers with 92-96% ee.
Subject Keywords
Organic-synthesis
,
Photorearrangement
URI
https://hdl.handle.net/11511/37386
Journal
Tetrahedron Asymmetry
DOI
https://doi.org/10.1016/s0957-4166(99)00080-4
Collections
Department of Chemistry, Article