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PLE catalysed enantiomeric separation of various (+/-)-6-acetoxy-alpha,beta-unsaturated cyclic ketones
Date
2001-01-01
Author
Tanyeli, Cihangir
Dikici, E
Fleischhauer, J
Repges, C
Wang, YK
Gawronski, J
Kacprzak, K
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Various (+/-)-6-acetoxy-alpha,beta -unsaturated cyclic ketones were resolved by PLE catalysed hydrolysis to afford enantiomerically enriched 6-hydroxy derivatives with 85-98% e.e. The absolute configuration of 6-hydroxy-alpha,beta -unsaturated cyclic ketones were determined via CD measurements.
Subject Keywords
Enantiomeric resolution
,
Esterases
,
Alpha '-hydroxy-alpha,beta-unsaturated cyclic ketones
,
PLE
URI
https://hdl.handle.net/11511/53989
Journal
ENANTIOMER
Collections
Department of Chemistry, Article
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C. Tanyeli et al., “PLE catalysed enantiomeric separation of various (+/-)-6-acetoxy-alpha,beta-unsaturated cyclic ketones,”
ENANTIOMER
, pp. 219–227, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/53989.