Thermal characterization of different origin class-G cements

In this study, thermal characteristics and kinetics of three different origin class-G cements (Mix, Bolu, and Nuh) were studied using thermogravimetry (TG/DTG) and differential scanning calorimeter (DSC). In DSC curves at different heating rates a number of peaks were observed consistently in different temperature intervals. TG/DTG is used to identify the detected phases and the corresponding mass loss. In the dehydration kinetic study of the different origin class-G cement samples, three different methods (Arrhenius, Kissinger, and Augis & Bennett) is used to determine the dehydration kinetic parameters of the cement samples and the results are discussed.


Thermal behavior and kinetics of crude oils at low heating rates by differential scanning calorimeter
Kök, Mustafa Verşan (2012-04-01)
The objective of this research was to investigate thermal behavior and kinetics of different origin crude oils in limestone matrix by differential scanning calorimeter (DSC) at low heating rates. In DSC experiments, three distinct reaction regions were identified in all of the crude oil + limestone mixtures known as low temperature oxidation (LTO), fuel deposition (FD) and high temperature oxidation (HTO) respectively. Kinetic analysis of the crude oil samples was determined by different models known as AST...
Thermal analysis applications in fossil fuel science - Literature survey
Kök, Mustafa Verşan (2002-01-01)
In this study, instances where thermal analysis techniques ( differential scanning calorimetry, thermogravimetry, differential thermal analysis, etc.) have been applied for fossil fuel characterisation and kinetics are reviewed. The scientific results presented clearly showed that thermal analysis is a well-established technique used in fossil fuel research area. The literature survey showed that thermal methods were important not only theoretically but also from a practical point of view.
Thermal decomposition of Tatarstan Ashal'cha heavy crude oil and its SARA fractions
Varfolomeev, Mikhail A.; Galukhin, Andrey; Nurgaliev, Danis K.; Kök, Mustafa Verşan (2016-12-15)
In this research, heavy crude oil from Ashal'cha field, Republic of Tatarstan, and its SARA (saturate, aromatic, resin and asphaltene) fractions were analyzed by differential scanning calorimetry (DSC) and thermogravimetry (TGA) methods. The experiments were performed at three different heating rates (10, 20, 30 degrees C/min) for DSC and at single heating rate for TGA analysis, all under the air atmosphere. In DSC experiments, two main reaction regions were detected at each heating rate known as low and hi...
Catalytic effects of metallic additives on the combustion properties of crude oils by thermal analysis techniques
Kök, Mustafa Verşan (2001-08-20)
Differential scanning calorimetry (DSC) was applied to crude oil combustion in the presence and absence of metal chlorides. It was observed that in the presence of smaller ratios of metallic additives, the surface reactions were predominant and the catalyst did not affect the reactions much. Three reaction regions were identified as low temperature oxidation (LTO), middle temperature oxidation (MTO) and high temperature oxidation (HTO). Kinetic parameters of the reaction regions were determined with two dif...
Simultaneous thermogravimetry-calorimetry study on the combustion of coal samples: Effect of heating rate
Kök, Mustafa Verşan (2012-01-01)
Combustion characteristics of two different coal samples were investigated using power compensating type differential scanning calorimeter (DSC) and thermogravimetry (TG-DTG) at different heating rates (5, 10 and 15 degrees C/min). Differential scanning calorimeter (DSC) and thermogravimetry (TG-DTG) curves revealed two main reaction regions at each heating rate studied. Reaction regions, peak and burn-out temperatures, weight loss and heat of reactions of the samples were determined. Kinetic parameters of ...
Citation Formats
M. V. Kök, “Thermal characterization of different origin class-G cements,” JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, pp. 1533–1539, 2014, Accessed: 00, 2020. [Online]. Available: