(2-Hydroxyethy1)hydraziniurn(2+) dichloride

Date

2005-05-01

Author

Turgut, G
Zora, Metin
Odabasoglu, M
Ersanli, CC
Buyukgungor, O

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

112
views

0
downloads

The crystal structure of the title compound, C2H10N2O2+&BULL; 2Cl(-), is built up from one 2-hydroxyethylhydrazinium(2+) cation and two Cl- anions. The molecular structure is stabilized by O-H&BULL;&BULL;&BULL; Cl and N-H&BULL;&BULL;&BULL; Cl hydrogen bonds. The crystal structure is stabilized by one N-H&BULL;&BULL;&BULL; O and three N-H&BULL;&BULL;&BULL; Cl interactions, and the three-dimensional network of hydrogen bonds stabilizes the crystal packing. All five hydrazinium H atoms are involved in hydrogen bonds to Cl- anions. The Cl&BULL;&BULL;&BULL; H contact distances range from 2.122 (15) to 2.809 (14) &ANGS;.

Subject Keywords

General Biochemistry, Genetics and Molecular Biology, General Medicine

URI

https://hdl.handle.net/11511/40933

Journal

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

DOI

https://doi.org/10.1107/s0108270105007183

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

1SR,2SR,3SR,4RS,5RS,6RS,7SR,8RS)-7,8-dichlorobicyclo[4.2.0]octa-2,3,4,5-tetrayl tetraacetate Sahin, Ertan; Kelebekli, Latif; Kara, Yunus; Balcı, Metin (International Union of Crystallography (IUCr), 2006-07-01) In the title compound, C16H20Cl2O8, the bicyclic system contains a central non-planar cyclohexane ring which is fused to a cyclobutane moiety. The cyclohexane ring has a chair conformation and the whole system adopts a syn conformation. The structure provides information on the stereochemical course of the chlorination, photo-oxidation and hydroxylation steps of the reaction.
Propynylferrocene and (phenylethynyl)ferrocene Zora, Metin; Tumay, Tulay Asli; Odabasoglu, Mustafa; Buyukgungor, Orhan (International Union of Crystallography (IUCr), 2006-08-01) The title compounds, propynylferrocene, [Fe(C5H5)(C8H7)], (I), and (phenylethynyl) ferrocene, [Fe(C5H5)(C13H9)], (II), are stabilized by weak C-H center dot center dot center dot pi interactions. The C C bond distances in these molecules are in the range 1.182 (3)-1.192 (3) angstrom. In (II), the ferrocenyl and phenyl groups are perpendicular, making an angle of 89.06 (13)degrees, which is a rare occurrence.
A promising enzyme anchoring probe for selective ethanol sensing in beverages Soylemez, Saniye; Goker, Seza; Toppare, Levent Kamil (Elsevier BV, 2019-07-15) A newly designed amperometric biosensor for the determination of ethanol through one-step electrochemical coating of (4,7-di(thiophen-2-yl)benzo[c][1,2,5]selenadiazole-co-1H-pyrrole-3-carboxylic acid) (TBeSe-co-P3CA) on a graphite electrode is presented. It was aimed to propose a newly synthesized copolymer with enhanced biosensing properties as a novel sensor for the quantification of ethanol. The conjugated copolymer (TBeSe-co-P3CA) was prepared through electrochemical polymerization by potential cycling....
Synthesis, Characterization and Evaluation of Cytotoxic Activities of Novel Aziridinyl Phosphonic Acid Derivatives Khan, Rehan; Ulusan, Sinem; Banerjee, Sreeparna; Doğan, Özdemir (Wiley, 2019-11-01) New aziridine 2-phosphonic acids were prepared by monohydrolysis of the aziridine 2-phosphonates that were obtained by the modified Gabriel-Cromwell reaction of vinyl phosphonate or alpha-tosylvinyl phosphonate with a primary amine or a chiral amine. The cellular cytotoxicity of these compounds was tested against the HCT-116 colorectal cancer cell lines and the CCD-18Co normal colon fibroblast lines using the MTT assay. Three of the synthesized phosphonic acid derivatives 2e (ethyl hydrogen {(2S)-1-[(1S)-1-...
FREE-RADICAL MEDIATED INTERACTION OF ASCORBIC-ACID AND ASCORBATE/CU(II) WITH VIRAL AND PLASMID DNAS ERDEM, G; ONER, C; Önal, Ahmet Muhtar; KISAKUREK, D; OGUS, A (Springer Science and Business Media LLC, 1994-03-01) Previous studies indicate that ascorbic acid, when combined with copper or iron cleaves several viral DNAs. In this study, we generated the ascorbate radical anion electrochemically in a simple chemical environment without the participation of a metal ion. This solution possesses viral DNA scission activity. The absence of catalytic metal ions [Fe (III) and Cu(II)] in the incubation medium was evidenced by metal chelating agents such as desferrioxamine and EDTA. The radical quenching at high EDTA concentrat...

Citation Formats

G. Turgut, M. Zora, M. Odabasoglu, C. Ersanli, and O. Buyukgungor, “(2-Hydroxyethy1)hydraziniurn(2+) dichloride,” ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, pp. 0–0, 2005, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/40933.