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Synthesis and electropolymerization of 5,12-dihydrothieno[3 ',4 ': 2,3][1,4]dioxocino[6,7-b]-quinoxaline and its electrochromic properties
Date
2007-08-01
Author
Ak, Mine Sulak
Ak, Metin
Guellue, Mustafa
Toppare, Levent Kamil
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Synthesis of a new thiophene-based monomer; 5,12-dihydrothieno[3',4':2,3][1,4]dioxocino[6,7-b]quinoxaline (DDQ), was realized. The chemical structure of the monomer was characterized by H-1 NMR, FTIR and mass spectroscopy techniques. Electrochemical polymerization of DDQ and characterization of the resulting polymer [P(DDQ)] was performed. Moreover, the spectroelectrochemical and electrochromic properties of the polymer film were investigated. P(DDQ) has a low oxidation potential (0.9 V) and low band gap (1.73 eV) compared to polythiophene. In addition, dual-type polymer electrochromic device (ECD) based on P(DDQ) with poly(3,4-ethylenedioxythiophene) (PEDOT) was constructed. Spectroelectrochemistry, electrochromic switching, stability and open-circuit stability of the device were studied. It was observed that polymer have good switching time, reasonable contrast and optical memory.
Subject Keywords
Organic Chemistry
,
General Physics and Astronomy
,
Polymers and Plastics
URI
https://hdl.handle.net/11511/41864
Journal
EUROPEAN POLYMER JOURNAL
DOI
https://doi.org/10.1016/j.eurpolymj.2007.05.029
Collections
Department of Chemistry, Article
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M. S. Ak, M. Ak, M. Guellue, and L. K. Toppare, “Synthesis and electropolymerization of 5,12-dihydrothieno[3 ‘,4 ’: 2,3][1,4]dioxocino[6,7-b]-quinoxaline and its electrochromic properties,”
EUROPEAN POLYMER JOURNAL
, pp. 3452–3460, 2007, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/41864.