SYNTHESIS AND CHARACTERIZATION OF POLY(DICHLOROPHENYLENE OXIDE)S BASED ON THE ELECTROOXIDATION OF BIS(2,4,6-TRICHLOROPHENOXO)BIS(PYRIDINE)COPPER(II) COMPLEX

Date

1993-01-01

Author

SEN, S
KISAKUREK, D

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Electroinitiated polymerization of bis(2,4,6-trichlorophenoxo)bis(pyridine)copper(II) complex was achieved in dimethylformamide by constant potential electrolysis under air and N2. The polymers obtained at several potentials were characterized by H-1 n.m.r., C-13 n.m.r., FTi.r. and d.s.c., and were found to be branched. The kinetics of the polymerization were followed by in situ cyclic voltammetry measurements at 13.5 and 20-degrees-C during electrolysis. As found for the thermal polymerization of this complex, electroinitiation begins after 50 min at 13.5-degrees-C, whereas the induction period is negligible for electrolysis at 20-degrees-C.

Subject Keywords

Organic Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/64775

Journal

POLYMER

DOI

https://doi.org/10.1016/0032-3861(93)90681-y

Collections

Department of Chemistry, Article

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Citation Formats

S. SEN and D. KISAKUREK, “SYNTHESIS AND CHARACTERIZATION OF POLY(DICHLOROPHENYLENE OXIDE)S BASED ON THE ELECTROOXIDATION OF BIS(2,4,6-TRICHLOROPHENOXO)BIS(PYRIDINE)COPPER(II) COMPLEX,” POLYMER, pp. 4146–4149, 1993, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/64775.