Application of ferrocenyl substituted aziridinylmethanols (FAM) as chiral ligands in enantioselective conjugate addition of diethylzinc to enones

Date

2007-03-30

Author

İŞLEYEN, Alper
Doğan, Özdemir

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Easily available ferrocenyl substituted aziridinylmethanol FAM-4a complexes with nickel and catalyzes the enantioselective diethylzinc addition to various enones with enantiomeric excesses reaching 80%. The ligand can be recovered and used without losing its activity. The sense of induction was found to be dependent on the configuration of the aziridine ring.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Catalysis

URI

https://hdl.handle.net/11511/42249

Journal

TETRAHEDRON-ASYMMETRY

DOI

https://doi.org/10.1016/j.tetasy.2007.02.015

Collections

Department of Chemistry, Article

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Citation Formats

A. İŞLEYEN and Ö. Doğan, “Application of ferrocenyl substituted aziridinylmethanols (FAM) as chiral ligands in enantioselective conjugate addition of diethylzinc to enones,” TETRAHEDRON-ASYMMETRY, pp. 679–684, 2007, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42249.