A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane

Date

2012-01-01

Author

Karahan, Senem
Zahmakıran, Mehmet
Özkar, Saim

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A new type of supported rhodium nanoparticles were reproducibly prepared from N(2)H(4)BH(3) reduction of [Rh(mu-Cl)(1,5-cod)](2) without using any solid support and pre-treatment technique. Their characterization shows the formation of well dispersed rhodium(0) nanoparticles within the framework of a polyaminoborane based polymeric support. These new rhodium(0) nanoparticles were found to be the most active supported catalyst in the catalytic dehydrogenation of ammonia-borane in water at room temperature.

Subject Keywords

Hydrogen generation, Nanoclusters catalyst, Hydrolysis, Boron, Stabilization, Dissociation, Carbon

URI

https://hdl.handle.net/11511/45083

Journal

CHEMICAL COMMUNICATIONS

DOI

https://doi.org/10.1039/c1cc15864c

Collections

Department of Chemistry, Article

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Citation Formats

S. Karahan, M. Zahmakıran, and S. Özkar, “A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane,” CHEMICAL COMMUNICATIONS, pp. 1180–1182, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/45083.