Date

2009-08-05

Author

AYDEMİR, MURAT
DURAP, FEYYAZ
BAYSAL, AKIN
AKBA, OSMAN
Gumgum, Bahattin
Özkar, Saim
Yildirim, Leyla Tatar

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Two new bis(diphenylphosphino)isopropylphenylamines, (PPh(2))(2)N-C(6)H(4)-CH(CH(3))(2), having the isopropyl substituent at the carbon atom 2 (1) or 4 (2), were prepared by the aminolysis of chlorodiphenylphosphine with isopropyl substituted aniline at the ortho- or para-position, respectively, under anaerobic conditions. Oxidation of 1 and 2 with either aqueous hydrogen peroxide, elemental sulfur or grey selenium in thf gave the corresponding oxides, sulfides and selenides (Ph(2)P=E)(2)N-C(6)H(4)-CH(CH(3))(2), where E = O, S or Se, respectively. The palladium and platinum complexes [M{(Ph(2)P)(2)N-C(6)H(4)-CH(CH(3))(2))Cl(2)] (M = Pd, Pt) and the copper complex [Cu((Ph(2)P)(2)N-C(6)H(4)-CH(CH(3))(2))(2)]PF(6) were isolated from the reaction of the bis(phosphino)anilines with MCl(2)(cod) or [Cu(CH(3)CN)(4)]PF(6), respectively. The new compounds were characterized by NMR, IR spectroscopy and elemental analysis. Furthermore, the solid-state structures of two representative complexes were determined using single crystal X-ray diffraction analysis. The compounds of palladium (1d) and platinum (1e), both mononuclear complexes, crystallize in the monoclinic P2(1)/c space group. In both compounds the metal ion has a distorted square-planar coordination geometry. The structural properties of complexes Id and le in the solid state are very similar. The palladium complexes were also tested for their catalytic activities in C-C coupling reactions.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Materials Chemistry

URI

https://hdl.handle.net/11511/63033

Collections

Department of Chemistry, Article