HINDERED LIGAND MOVEMENTS IN TRANSITION-METAL COMPLEXES .14. DYNAMIC BEHAVIOR OF NU-DIENECHROMIUM(0) AND MOLYBDENUM(0) COMPLEXES

Date

1978-01-01

Author

KREITER, CG
Özkar, Saim

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The stereochemistry of tetracarbonyl-η-1,5-cyclooctadienechromium(0) (, tetracarbonyl-η-1,3-butadienechromium(0) (, mer-tricarbonyltrimethylphosphite-η-1,5-cyclooctadienechromium(0) (, fac-tricarbonyltrimethylphosphite-η-1,3-butadienechromium(0) ()l and cis-dicarbonyldi-η-1,3-butadienemolybdenum(0) () has been investigated by 1H and 13C NMR spectroscopy. , , and show temperature-dependent 13C NMR spectra, according to thermally activated polytopal rearrangements, possibly via trigonal prismatic transition states.

URI

https://hdl.handle.net/11511/70014

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY

DOI

https://doi.org/10.1016/s0022-328x(00)81283-8

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Department of Chemistry, Article

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Citation Formats

C. KREITER and S. Özkar, “HINDERED LIGAND MOVEMENTS IN TRANSITION-METAL COMPLEXES .14. DYNAMIC BEHAVIOR OF NU-DIENECHROMIUM(0) AND MOLYBDENUM(0) COMPLEXES,” JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp. 0–0, 1978, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/70014.