Silver Nanowire/Conducting Polymer Nanocomposite Electrochromic Supercapacitor Electrodes

2017-01-01
YÜKSEL, Recep
COŞKUN, Sahin
Günbaş, Emrullah Görkem
Çırpan, Ali
Toppare, Levent Kamil
Ünalan, Hüsnü Emrah
Show full item record
Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
166
views
0
downloads
Color-changing energy storage devices that can easily communicate with the user carry the potential to be integrated into smart electronics. In this work, nanocomposite electrochromic supercapacitor electrodes were fabricated with silver nanowire (Ag NW) network electrodes and a green to transmissive electrochromic polymer, PDOPEQ. High transparency and conductivity of Ag NW network current collectors allowed the fabrication of electrochromic supercapacitors and investigation of the spectroelectrochemical and electrochemical properties of the PDOPEQ. Previously reported electrochromic properties such as long term electrochromic switching stability and vibrant color change for PDOPEQ were well transferred into electrochromic capacitors. Investigated electrochromic supercapacitors changed their color from vibrant green to transparent with superior characteristics. Specific capacitance of the fabricated nanocomposite electrodes was calculated as 61.5 F g(-1) at a current density of 0.1 A g(-1) and to the best of our knowledge, one of the highest capacity retention value was obtained upon 20000 galvanostatic charge-discharge cycles. With these color options and electrochemical performance, investigated conducting polymer (CP) holds strong promise to be used in electrochromic supercapacitors. (C) 2017 The Electrochemical Society. All rights reserved.
Renewable Energy, Sustainability and the Environment, Electrochemistry, Materials Chemistry, Electronic, Optical and Magnetic Materials, Surfaces, Coatings and Films, Condensed Matter Physics
https://hdl.handle.net/11511/38451
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Department of Chemistry, Article

Suggestions

All-Organic Electrochromic Supercapacitor Electrodes
YÜKSEL, Recep; CEVHER, ŞEVKİ CAN; Çırpan, Ali; Toppare, Levent Kamil; Ünalan, Hüsnü Emrah (The Electrochemical Society, 2015-01-01)
The need for determining the instant capacity of an energy storage device has led to the integration of an indicator gauge in batteries. Consumers only have to press the contact points on the battery to activate a thermochromic indicator, which measures the heat resistance of the device. This can be implemented in a supercapacitor through electrochromism, eliminating the necessity to press on the contact points. With this motivation, here we report on the fabrication and characterization of all-organic mult...
Silver Nanoparticles Added Polymer Film Prepared by Electrochemical Route for Surface Enhanced Raman Scattering Applications
Khadim, Raisan; Uzun, Ceren; Cihaner, Atilla; Kaya, Murat (The Electrochemical Society, 2019-03-02)
A simplemethod for the fabrication of stable and highly active surface enhanced Raman scattering (SERS) substrate by exploiting the optical properties of the silver nanoparticles (AgNPs) and organizational characteristics of the polymer is presented. Homogeneous distribution ofAgNPs is achieved with the usage of poly (4,7-di-2,3-dihydrothieno [3,4-b] [1,4] dioxin-5-yl-2,1,3 benzoselena diazole) (PESeE) film coated on the indium tin oxide glass (ITO) surface. The obtained structure ensured the emergence of a...
Fluid, Strain and Rotation Sensing Applications by Using Metamaterial Based Sensor
ALTINTAŞ, OLCAY; AKSOY, MURAT; AKGÖL, OĞUZHAN; ÜNAL, EMİN; KARAASLAN, MUHARREM; Sabah, Cumali (The Electrochemical Society, 2017-01-01)
We propose a design of a metamaterial based sensor to be used in various applications including micro-fluid, strain and rotation sensing. The structure has a simple geometry composed of a single circular split ring resonator (CSRR) and it is possible to adjust the resonance frequency in the region of desired band. The resonance frequency is carefully selected so that the materials to be sensed have linear dielectric curves at that particular frequency range which iscrucial to design accurate sensing charact...
Paper Based Glucose Biosensor Using Graphene Modified with a Conducting Polymer and Gold Nanoparticles
GOKOGLAN, Tugba Ceren; KESİK, Melis; SOYLEMEZ, Saniye; YÜKSEL, Recep; Ünalan, Hüsnü Emrah; Toppare, Levent Kamil (The Electrochemical Society, 2017-01-01)
In this work a novel approach was reported for glucose detection using disposable paper based electrodes consisting graphene modified with a conducting polymer, glucose oxidase (GOx) and gold nanoparticles. For the first time, a conducting polymer; poly(9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl)-end capped with 2,5-diphenyl-1,2,4-oxadiazole (PFLO) was spread over graphene coated papers and used as a matrix for glucose detection. To finalize the desired biosensor, the enzyme GOx was immobilized with gold nano...
Quantum Transport Mode in Graphene Nanoribbon Based Transistor
Hedayat, Sayed Norollah; Ahmadi, Mohammad Taghi; Sedghi, Hassan; Goudarzi, Hadi; Moradi, Shahram (American Scientific Publishers, 2017-09-01)
Graphene has incredible carrier transport property with high application opportunity at single molecule level, which composes it as promising materials on nano electronic application. In order to develop the new device such as graphene nanoribbon transistor, Carbon Nanotube Field Effect Transistor (CNTFET) and nanowire based devices, it is essential to investigate the quantum limit in low dimensional systems. In this paper transmission coefficient of the schottky structure in the graphene based transistor i...
Citation Formats
R. YÜKSEL, S. COŞKUN, E. G. Günbaş, A. Çırpan, L. K. Toppare, and H. E. Ünalan, “Silver Nanowire/Conducting Polymer Nanocomposite Electrochromic Supercapacitor Electrodes,” JOURNAL OF THE ELECTROCHEMICAL SOCIETY, pp. 0–0, 2017, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38451.
METU IIS - Integrated Information Service open@metu.edu.tr