Studies on the effect of electrode type and substrate temperature on plasma polymerization of two model compounds: Acrylonitrile and hexamethyldisiloxane

1990-4
Akovalı, Güneri
Dilsiz, Nursel
Polymers were prepared from saturated (HMDS) and unsaturated (AN) monomers in a radio frequency discharge (plasma). The effect of selected parameters such as electrode type (such as Cu, Zn, Ni, Al), reactor type, and substrate temperature (other parameters constant) on chemical structure and the rate of polymer deposition was examined by Fourier transform infrared (FTIR) spectroscopy. Differences in the nature of electrodes and reactor types were found to yield similar plasma products with similar rates of deposition for two monomers. In the tubular reactor used, deposition rates were observed to decrease with increasing substrate temperatures showing different dependencies on temperature for the monomers tested.
Polymer Engineering and Science

Suggestions

Effects of nucleating agent and processing conditions on the mechanical, thermal, and optical properties of biaxially oriented polypropylene films
Yuksekkalayci, C; Yılmazer, Ülkü; Orbey, N (Wiley, 1999-07-01)
The effects of nucleating agent, temperature of crystallization, and degree of machine direction (MD) orientation on the mechanical, optical, and thermal properties of biaxially oriented polypropylene (BOPP) films were investigated. Addition of nucleating agent improved only the initial tear resistance in the MD; however, the other mechanical and optical properties did not change appreciably. Ln the set of experiments in which the crystallization temperature was increased, the degree of crystallinity also i...
The Main Electrical and Interfacial Properties of Benzotriazole and Fluorene Based Organic Devices
Yildiz, Dilber E.; APAYDIN, Dogukan H.; KAYA, Emine; Altindal, Semsettin; Çırpan, Ali (Informa UK Limited, 2013-01-01)
Electrical and interfacial properties of ITO/PEDOT:PSS/poly((9,9-dioctylfluorene)-2,7-diyl(2-dodecyl-benzo[1,2,3]triazole)) (PFTBT)/Au devices were investigated using current-voltage (I-V), capacitance-voltage (C-V) and conductance-voltage (G/w-V) measurements at room temperature. The forward and reverse C-V and G/w-V measurements were carried out in the frequency range of 10kHz-1MHz. The electrical parameters, barrier height (phi Bo ) and ideality factor (n) obtained from the forward bias LnI-V plot were f...
Comparison of Natural Halloysite With Synthetic Carbon Nanotubes in Poly(lactic acid) Based Composites
Erpek, Canan Esma Yeniova; ÖZKOÇ, GÜRALP; Yılmazer, Ülkü (Wiley, 2017-11-01)
The objective of this study is to compare the mechanical properties, structure and degradability of the nanocomposites prepared with tubular nanofillers, halloysite (HNT) and carbon nanotube (CNT) in poly(lactic acid) (PLA), and thermoplastic polyurethane (TPU) toughened PLA (T-PLA) matrices. In the PLA matrix, CNT increased, whereas HNT decreased the tensile strength with increasing filler content. Also, the elongation at break and impact strength decreased with increasing CNT content, but these properties...
Simultaneous novel synthesis of conducting, nonconducting, and crosslinked polymers by microwave initiation
Çelik, Güler (Wiley, 2006-12-15)
A novel synthesis of poly(dibromophenylene oxide) (P), conducting polymer (CP), and/or crosslinked polymer (CLP), and/or radical ion polymers (RIP) was achieved simultaneously from sodium 2,4,6-tribromophenolate by microwave energy in a very short-time interval. The synthesized polymers were characterized via elemental analysis, FTIR, H-1 NMR and C-13 NMR, X-ray diffraction spectroscopy, SEM, DSC, TGA, ESR, GPC, conductivity measurement, and light scattering. It was found that polymerization proceeds throug...
Flow induced polymer-filler interactions: Bound polymer properties and bound polymer-free polymer phase separation and subsequent phase inversion during mixing
Akay, G. (Wiley, 1990-11)
The irreversible absorption of macromolecules on to solid filler particles during mixing in the melt is investigated. The molecular weight and concentration dependence of the absorbed layer thickness are evaluated and the chemical and morphological nature of the irreversibly absorbed polymer (bound polymer) are determined. It is found that the thickness of the bound polymer is not only dependent on the filler concentration but also dependent on polymer molecular weight. Bound polymer in high density polyeth...
Citation Formats
G. Akovalı and N. Dilsiz, “Studies on the effect of electrode type and substrate temperature on plasma polymerization of two model compounds: Acrylonitrile and hexamethyldisiloxane,” Polymer Engineering and Science, pp. 485–489, 1990, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51409.